| Primary crops (available studies) | Crop groups | Crops | Applications | Sampling | Comment/source |
|---|---|---|---|---|---|
| Root crops | Sugar beet | Foliar: 4 × 0.29 kg/ha; interval 14 days | 7 DALA: roots, tops, leaves | [U‐14C‐phenyl] prothioconazole (EFSA, 2014) | |
| Foliar: 4 × 0.29 kg/ha; interval 14 days | 7 DALA: roots, tops, leaves | [3,5‐14C‐triazole] prothioconazole (EFSA, 2014) | |||
| Cereals/grass | Wheat | Foliar (spring wheat): 2 × 0.22 kg/ha; BBCH 32–65 |
6 DALA: forage 26 DALA: hay 48 DALA: grain and straw |
[U‐14C‐phenyl] prothioconazole (EFSA, 2007b) | |
| Foliar (summer wheat): 2 × 0.25 kg/ha; interval 27 days (BBCH 31–59) |
0, 14 DALA: forage 48 DALA: grain and straw |
[3,5‐14C‐triazole] prothioconazole‐desthio (EFSA, 2007b) | |||
| Foliar (spring wheat): 2 × 0.18/0.29 kg/ha; BBCH 32–65 | Forage, hay, grain, straw | [3,5‐14C‐triazole] prothioconazole (EFSA, 2014) | |||
| Seed (spring wheat): 1 × 0.02 or 0.10 kg/100 kg seeds (ca. 220 kg seeds/ha) |
57 DAT: forage 110 DAT: hay 153 DAT: grain and straw |
[U‐14C‐phenyl] prothioconazole (EFSA, 2007b) | |||
| Pulses/oilseeds | Peanuts | Foliar: 3 × 0.3 kg/ha; interval 21 days (BBCH 66–75) | 14 DALA: hays and nuts without shells | [U‐14C‐phenyl] prothioconazole (EFSA, 2007b) | |
| Foliar: 3 × 0.3 kg/ha; interval 21 days (BBCH 66–75) | 14 DALA: hays and nuts without shells | [3,5‐14C‐triazole] prothioconazole (EFSA, 2014) |
| Rotational crops (available studies) | Crop groups | Crops | Application | PBI (DAT) | Comment/source |
|---|---|---|---|---|---|
| Root/tuber crops | Turnips | Soil, 0.58 kg/ha | 94, 201, 349 (roots, tops) | [U‐14C‐phenyl] prothioconazole (EFSA, 2007b) | |
| Leafy crops | Swiss chards | 80, 188, 348 | |||
| Cereals (small grain) | Spring wheat | Green material: 73, 178, 327Hay: 111, 231, 377Grain, straw: 1445, 269, 412 |
| Processed commodities (hydrolysis study) | Conditions | Stable | Comment/Source |
|---|---|---|---|
| Pasteurisation (20 min, 90°C, pH 4) | Yes | Prothioconazole degrades to prothioconazole‐desthio under sterilisation process (≤ 11% AR). Prothioconazole‐desthio remains stable (99.4–99.9% of AR) (United Kingdom, 2018) | |
| Baking, brewing and boiling (60 min, 100°C, pH 5) | Yes | ||
| Sterilisation (20 min, 120°C, pH 6) | Yes |