Table 2. Glass Transition Temperatures (T_g), Crystal Fraction (X_C), Mobile Amorphous Weight Fraction (X_MAF), Rigid Amorphous Weight Fraction (X_RAF), Experimental Elastic Modulus (E), Tensile Strength at Break (TS), and Elongation at Break Measured at T_room for PLLA after Crystallization at T_mold = 95 and 110 °C for Different Molding Times.

condition	Tg (°C)a	XCb	XMAFb	XRAFc	E (GPa)	TS (MPa)	elongation at break (%)
amorphous	57.0	0.00	1.00	0.00	3.60 ± 0.19	60.3 ± 2.2	3.60 ± 0.50
Tmold = 95 °C, tmold = 15 min	59.0	0.29	0.48	0.23	3.86 ± 0.18	58.6 ± 1.2	1.68 ± 0.10
Tmold = 95 °C, tmold = 30 min	63.5	0.38	0.39	0.23	3.83 ± 0.14	57.8 ± 1.1	1.68 ± 0.10
Tmold = 95 °C, tmold = 40 min	64.5	0.39	0.38	0.23	3.82 ± 0.20	57.9 ± 2.7	1.67 ± 0.10
Tmold = 95 °C, tmold = 50 min	65.0	0.40	0.36	0.24	3.92 ± 0.17	54.6 ± 1.7	1.60 ± 0.10
Tmold = 110 °C, tmold = 5 min	58.0	0.18	0.75	0.07	3.95 ± 0.22	50.8 ± 3.0	1.37 ± 0.10
Tmold = 110 °C, tmold = 10 min	60.0	0.38	0.47	0.15	4.08 ± 0.22	50.8 ± 3.2	1.36 ± 0.17
Tmold = 110 °C, tmold = 15 min	61.0	0.40	0.42	0.18	4.19 ± 0.19	50.6 ± 2.5	1.31 ± 0.15
Tmold = 110 °C, tmold = 20 min	62.0	0.42	0.38	0.20	4.42 ± 0.10	49.7 ± 3.0	1.24 ± 0.24

^aEstimated error from repeated measurements: ±0.5 K.

^bEstimated error from repeated measurements: ±0.02.

^cEstimated errors from repeated measurements: ±0.04.