Fig. 2. UV-Vis (a) and CD spectra (b) of (R)-1 recorded upon cooling a monomer solution from 363 K (red spectra) to 293 K (blue spectra → Agg I) and upon solvophobic quenching (cyan spectra → Agg II) at c = 5 × 10–6 M. (c) Time-dependent evolution of Agg II (UV-Vis, λ = 399 nm) after injection of molecularly dissolved 1 in CHCl3 into MCH at different final concentrations. At higher concentrations, the onset of the clustering process is shifted to shorter lag times, indicating a consecutive pathway.
