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. 2020 Aug 29;319:114164. doi: 10.1016/j.molliq.2020.114164

Table 2.

Ionic strength and temperature dependence parameters according to Debye-Hückel (EDH, molar concentration scale) and SIT (molal concentration scale) models (p = 0.1 MPa).

EDH log Kθ iH0 Ci
ATi C'i
NaCl (CH3)4NCl (C2H5)4NI NaCl
i=1a 9.937 ± 0.008b 0.226 ± 0.005b 0.271 ± 0.005b 0.69 ± 0.02b −27.4 ± 0.9b 2.0 ± 0.8b
i = 2 3.274 ± 0.008 0.180 ± 0.006 0.287 ± 0.008 0.58 ± 0.03 −2.9 ± 0.9 3.1 ± 0.7



SIT log Kθ iH0 ∆εi
∆Hi 00 ∆εi
NaCl (CH3)4NCl (C2H5)4NI NaCl
i = 1 9.947 ± 0.009 0.204 ± 0.006 0.173 ± 0.009 0.55 ± 0.02 −27.4 ± 0.9 1.7 ± 0.9
i = 2 3.284 ± 0.010 0.158 ± 0.006 0.179 ± 0.011 0.43 ± 0.03 −2.9 ± 1.0 2.7 ± 0.8
a

Protonation step, see Eq. (1a).

b

95% confidence interval (C.I.) = 2ur (relative standard uncertainty on log10KH); standard uncertainties: u(T) = 0.1 K, u(p) = 1 kPa.