Table 2.
EDH | log Kθ iH0 |
Ci |
ATi |
C'i |
||
---|---|---|---|---|---|---|
NaCl | (CH3)4NCl | (C2H5)4NI | NaCl | |||
i=1a | 9.937 ± 0.008b | 0.226 ± 0.005b | 0.271 ± 0.005b | 0.69 ± 0.02b | −27.4 ± 0.9b | 2.0 ± 0.8b |
i = 2 | 3.274 ± 0.008 | 0.180 ± 0.006 | 0.287 ± 0.008 | 0.58 ± 0.03 | −2.9 ± 0.9 | 3.1 ± 0.7 |
SIT | log Kθ iH0 |
∆εi |
∆Hi 00 |
∆εi′ |
||
---|---|---|---|---|---|---|
NaCl | (CH3)4NCl | (C2H5)4NI | NaCl | |||
i = 1 | 9.947 ± 0.009 | 0.204 ± 0.006 | 0.173 ± 0.009 | 0.55 ± 0.02 | −27.4 ± 0.9 | 1.7 ± 0.9 |
i = 2 | 3.284 ± 0.010 | 0.158 ± 0.006 | 0.179 ± 0.011 | 0.43 ± 0.03 | −2.9 ± 1.0 | 2.7 ± 0.8 |
Protonation step, see Eq. (1a).
95% confidence interval (C.I.) = 2ur (relative standard uncertainty on log10KH); standard uncertainties: u(T) = 0.1 K, u(p) = 1 kPa.