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. 2020 Aug 29;319:114164. doi: 10.1016/j.molliq.2020.114164

Table 4.

Overalla equilibrium constants of the M2+/NAC2− species in NaCl(aq) in the molar concentration scale at T = 298.15 K and at p = 0.1 MPa.

I/mol dm−3 CaL0(aq) CaHL+ CaL22−
0.098 1.36 ± 0.04b 10.22 ± 0.03b 3.82 ± 0.02b
0.135 1.29 ± 0.03 10.16 ± 0.03 3.75 ± 0.02
0.485 1.13 ± 0.02 10.04 ± 0.04 3.64 ± 0.03
0.736 1.17 ± 0.04 10.12 ± 0.06 3.71 ± 0.05
0.960 1.25 ± 0.06 10.22 ± 0.07 3.82 ± 0.07



I/mol dm−3 MgL0(aq) MgHL+
0.113 2.05 ± 0.02 11.38 ± 0.02
0.148 2.01 ± 0.02 11.34 ± 0.02
0.385 1.93 ± 0.02 11.31 ± 0.01
0.854 2.13 ± 0.06 11.61 ± 0.06
1.052 2.26 ± 0.07 11.78 ± 0.09



I/mol dm−3 ZnL0(aq) ZnLH+ ZnL(OH) ZnL22− ZnL2(OH)3− ZnL34−
0.134 5.58 ± 0.04 11.28 ± 0.07 −2.96 ± 0.15 11.22 ± 0.03 1.42 ± 0.05 14.87 ± 0.09
0.495 5.59 ± 0.05 11.04 ± 0.09 −2.99 ± 0.19 11.09 ± 0.03 1.47 ± 0.06 14.81 ± 0.12
0.742 5.76 ± 0.05 11.03 ± 0.11 −2.89 ± 0.22 11.15 ± 0.04 1.55 ± 0.07 14.77 ± 0.14
1.057 6.03 ± 0.07 11.08 ± 0.14 −2.72 ± 0.28 11.30 ± 0.05 1.66 ± 0.09 14.71 ± 0.18
a

log βMHiL values refer to Eq. (1b).

b

95% Confidence interval; standard uncertainties u are: u(c) = 0.001 mol dm−3, u(T) = 0.1 K, u(p) = 1 kPa.