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. 2020 Aug 29;319:114164. doi: 10.1016/j.molliq.2020.114164

Table 6.

Summary of the ionic strength dependence parameters of Eq. (13) for all the M2+/NAC2− species obtained analyzing experimental and literature data at T = 298.15 K and at p = 0.1 MPa.

Species p* z* Yθ (log β0)a ∂Y∂T
CaL0(aq) 1 8 2.17 ± 0.08b
CaHL+ 2 8 10.77 ± 0.12
CaL22− 2 8 4.80 ± 0.16
MgL0(aq) 1 8 3.01 ± 0.14
MgHL+ 2 8 12.14 ± 0.10
ZnL0(aq) 1 8 6.49 ± 0.09 −0.010c
ZnHL+ 2 8 11.76 ± 0.10
ZnL22− 2 8 12.23 ± 0.09 0.006c
ZnL34− 3 0 15.2 ± 0.2 −0.004c
ZnL2(OH)3− 1 2 2.7 ± 0.2 −0.070c
ZnL(OH) 0 6 −1.0 ± 0.2 −0.015c



Yθ
c0 0.76 ± 0.09
c1 0.11 ± 0.02
a

log β0MHiL values refer to Eq. (1b).

b

95% Confidence interval.

c

Tentative values, valid at I = 0.15 mol dm−3, obtained from comparison with NIST data [62] (see text); standard uncertainties: u(T) = 0.1 K, u(p) = 1 kPa.