Table 1.
Sample | θw | θbr | θform | γs− | ΔGsLW | ΔGsAB | ΔGsTOT |
---|---|---|---|---|---|---|---|
PDMS | 113.6° ± 0.6 | 87.6° ± 1.8 | 111.2° ± 0.6 | 4.5 ± 0.9 | −2.9 ± 0.5 | −58.9 ± 4.3 | −61.8 ± 4.4 |
p-CNT/PDMS | 117.0° ± 0.7 | 80.4° ± 0.7 | 110.4° ± 0.8 | 2.5 ± 0.4 | −1.2 ± 0.1 | −70.2 ± 2.9 | −71.4 ± 2.9 |
f-CNT/PDMS | 116.6° ± 0.6 | 76.6° ± 1.5 | 111.1° ± 0.5 | 3.0 ± 0.6 | −0.6 ± 0.2 | −67.0 ± 3.7 | −67.7 ± 3.7 |
p-BM/PDMS | 121.5° ± 0.3 | 88.8° ± 0.9 | 115.7° ± 0.4 | 1.9 ± 0.3 | −3.2 ± 0.3 | −73.8 ± 2.2 | −77.1 ± 2.2 |
f-BM/PDMS | 113.6° ± 0.4 | 71.3° ± 1.4 | 109.1° ± 0.6 | 4.0 ± 0.7 | −0.1 ± 0.1 | −61.5 ± 3.3 | −61.7 ± 3.3 |
p-THF/PDMS | 116.6° ± 0.3 | 80.5° ± 1.7 | 112.0° ± 0.5 | 3.2 ± 0.7 | −1.2 ± 0.3 | −65.7 ± 3.8 | −67.0 ± 3.8 |
f-THF/PDMS | 125.6° ± 0.4 | 92.3° ± 1.5 | 118.6° ± 0.9 | 1.2 ± 0.4 | −4.3 ± 0.5 | −80.1 ± 3.7 | −84.5 ± 3.8 |
θw, θbr and θform: the average of measured contact angles with water, α-bromonaphthalene and formamide, respectively; γs−: electron donor parameter; ΔGsLW and ΔGsAB: Lifshitz–van der Waals and acid-base free energies of the surface, respectively; ΔGsTOT: free energy of interaction between two entities of the surfaces immersed in water. Values of γs−, ΔGsLW, ΔGsAB and ΔGsTOT are in mJ m−2.