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. Author manuscript; available in PMC: 2020 Sep 1.
Published in final edited form as: Nat Catal. 2019 Aug 12;2(9):756–762. doi: 10.1038/s41929-019-0330-7

Fig. 4. Use of Feedstock Alkenes and Asymmetric Synthesis.

Fig. 4.

a and b, Synthesis of α-methyl and α-ethyl branched amines from the feedstock chemicals ethylene and propylene, respectively. c, Large scale (> 5 g) modular synthesis of Boc-protected α-methyl branched amine with 1 mol % [Cp*RhCl2]2 loading. d, Asymmetric catalysis with chiral catalyst 59. One equivalent of NaHCO3 was used as an additive for oxime C–H bond substrates. a Reactions performed on 0.05 mmol scale. b Reaction performed on 0.2 mmol scale.