Table 2.
Characteristic enthalpies and temperatures of bicomponent fibres with PGSu additive in relation to PLLA and PLCL determined from differential scanning calorimetry (DSC).
Sample Name | Tg of PGSu [°C] a | Tg of PLLA [°C] | Enthalpy of Relaxation of PLLA [J/g] | Relaxation Temperature of PLLA [°C] | Cold Crystallisation [J/g] | Tc of PLLA [°C] | Enthalpy of Crystal Phase Melting [J/g] | Tm [°C] | Sample Name | Tg of PGSu [°C] | Enthalpy of Crystal Phase Melting [J/g] | Tm [°C] |
---|---|---|---|---|---|---|---|---|---|---|---|---|
PLLA0 | b | 50.87 | 15.99 | 55.32 | 13.64 | 67.57 | 45.02 | 180.80 | PLCL0 | - | 24.89 | 157.24 |
PLLA2 | - | 50.84 | 10.65 | 56.6 | 16.71 | 66.78 | 53.54 | 182.66 | PLCL2 | - | 24.93 | 156.98 |
PLLA5 | −32.53 | 50.72 | 9.39 | 56.67 | 15.52 | 67.44 | 53.301 | 182.41 | PLCL5 | −15.98 | 25.26 | 157.78 |
PLLA10 | −32.58 | 50.55 | 8.92 | 56.66 | 15.57 | 67.64 | 51.08 | 181.07 | PLCL10 | −20.56 | 29.66 | 157.04 |
PLLA20 | −30.92 | 49.21 | 7.86 | 56.97 | 11.36 | 67.89 | 32.58 | 180.18 | PLCL20 | −25.20 | 31.45 | 157.11 |
PLLA40 | −27.83 | 48.34 | 2.71 | 59.92 | 12.14 | 71.98 | 16.04 | 180.12 | PLCL40 | −30.96 | 27.04 | 156.28 |
aTg of PGSu = −38.13 °C; b Tg of PGSu was not observed.