Table 6.

Molecular characteristics of the HSISH and HISIH pentablock terpolymers and their micellar characteristics in n-heptane and n-dodecane.

Sample	Ð a	%S, wt b	%I wt b	%H wt b	Solvent	Mw × 10−3 c	A2 c	Rh d, nm	kD d	Nw
HSISH	1.25	46	41	13	THF	99.250	5.2 × 10−4	13.6	53.6	-
					C7	21,600.00	1.68 × 10−6	32.5 62.8(54%) e	30.1–32.2	217.6
					C12	62,000.00	1.55 × 10−7	39.0 93.2(53%) e	38.4–39.6	624.7
HISIH	1.32	43	32	25	THF	169.00	0.15	17.0	42.7	-
					C7	717.00	0.12	47.1 109.4(49%) e	38.3 0.05	4.24
					C12	1492.30	0.26	32.0 78.4(58%) e	12.7 4.7	8.83

^a By SEC in THF, ^b by ¹H NMR in CDCl₃ at 25 °C, ^c by LALLS, ^d by DLS in n-heptane or n-dodecane and ^e by CONTIN analysis.