Table 4.
Catalysts | NTP Technology | Operative Conditions | H2S Conversion (%) | Ref. |
---|---|---|---|---|
CdS/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
90.9 | [66] |
ZnS/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
82.9 | [66] |
Zn0.4Cd0.6S/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
97.9 | [66] |
Zn0.6Cd0.4S/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
100 | [68] |
Zn0.2Cd0.8S/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
92.8 | [68] |
Zn0.8Cd0.2S/Al2O3 | DBD | 10 kHz, 6.12 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
84.9 | [68] |
Cr0.20–ZnS/Al2O3 | DBD | 10 kHz, 5.57 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
100 | [69] |
Cr0.25–ZnS/Al2O3 | DBD | 10 kHz, 5.57 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
89.7 | [69] |
Cr0.15–ZnS/Al2O3 | DBD | 10 kHz, 5.57 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
87.4 | [69] |
Cr0.10–ZnS/Al2O3 | DBD | 10 kHz, 5.57 eV/H2 20% O2 in Ar Reacting flow rate: 30 mL min−1 1 atm, 120 °C |
81.8 | [69] |
1-wt% MoS2/Al2O3 | DBD | 10 kHz, 95 kJ·L−1 H2S/CO2 ratio = 20:15 Reacting flow rate: 35 mL min−1 1 atm, 120 °C |
94 | [70] |
5-wt% MoS2/Al2O3 | DBD | 10 kHz, 95 kJ·L−1 H2S/CO2 ratio = 20:15 Reacting flow rate: 35 mL min−1 1 atm, 120 °C |
99 | [70] |
10-wt% MoS2/Al2O3 | DBD | 10 kHz, 95 kJ·L−1 H2S/CO2 ratio = 20:15 Reacting flow rate: 35 mL min−1 1 atm, 120 °C |
97 | [70] |
15-wt% MoS2/Al2O3 | DBD | 10 kHz, 95 kJ·L−1 H2S/CO2 ratio = 20:15 Reacting flow rate: 35 mL·min−1 1 atm, 120 °C |
92 | [70] |
3-wt% MoOx/Al2O3 | DBD | 10 kHz, 1 W 5% H2S/Ar Reacting flow rate: 150 mL min−1 1 atm, 160 °C |
48 | [71] |
5-wt% MoOx/Al2O3 | DBD | 10 kHz, 1 W 5% H2S/Ar Reacting flow rate: 150 mL min−1 1 atm, 160 °C |
52 | [71] |
7-wt% MoOx/Al2O3 | DBD | 10 kHz, 1 W 5% H2S/Ar Reacting flow rate: 150 mL min−1 1 atm, 160 °C |
45 | [71] |
Fe/WSAC Treated for 10 min at 6.8 kV |
DBD | 7.8 kHz, 6.8 kV 500 ppm of H2S in N2 Reacting flow rate: 60 mL min−1 1 atm, 60 °C |
100 for 270 min | [72] |
Fe/WSAC Treated for 10 min at 6.8 kV with a gas gap of 5.5 mm and a dielectric thickness of 1.5 mm |
DBD | 7.8 kHz, 6.8 kV 500 ppm of H2S in N2 Reacting flow rate: 60 mL min−1 1 atm, 60 °C |
100 for 210 min | [73] |
La0.9MnO3 | DBD | 10 kHz, 593.7 J·L−1 100 ppm of H2S in air Reacting flow rate: 2 L min−1 1 atm, 80 °C |
96.4 | [74] |
Mn2O3 | DBD | 50 Hz, 22 kV 200 mg m−3 H2S, 1200-mg·m−3 O3 in air Reacting flow rate: 0.2 m3 h−1 |
100 | [75] |
Ag2O | DBD | 50 Hz, 22 kV 200 mg m−3 H2S, 1200-mg m−3 O3 in air Reacting flow rate: 0.2 m3 h−1 |
98 | [75] |
CuO | DBD | 50 Hz, 22 kV 200 mg m−3 H2S, 1200-mg·m−3 O3 in air Reacting flow rate: 0.2 m3 h−1 |
82 | [75] |
Fe2O3 | DBD | 50 Hz, 22 kV 200 mg m−3 H2S, 1200-mg m−3 O3 in air Reacting flow rate: 0.2 m3 h−1 |
75 | [75] |