Skip to main content
. 2020 Aug 14;10(8):1596. doi: 10.3390/nano10081596

Table 5.

Operative conditions and efficiency for NOx-removal via NTP technology.

Catalytic Removal via NTP Technology
Catalyst Formulation NTP Technology Operative Conditions NOx Removal Efficiency %
(Maximum Value Reached)
Reference
Ag/Al2O3 DBD 16–23 kHz, 1–2 W
Reacting flow rate: 276 cm3 min−1
NO: 720 ppm
Either 540 ppm n-C8H18 or 620 ppm toluene
4.3% O2
7.2% H2O
7.2% CO2
He as carrier gas
1 atm, 25–250 °C
70 [80]
Ag/α-Al2O3 DBD 2 W
Reacting flow rate: 2 L min−1
NO: 300 ppm
10% O2
3.2% H2O
265 ppm n-heptane
N2 as balance gas
74 [81]
H–MOR
Co–MOR
NMOR
DBD 5 W
Reacting flow rate: 60 mL min−1
NO: 2130 ppm
8% O2
He as balance gas
T = 35 °C
99.6 [82]
Co/Ba/Al
Pd/Co/Ba/Al
Pd particle size = 3.1 nm
Pt/Ba/Al
Pt particle size = 2.7 nm
DBD 40 kHz, 20 W (in the rich phase)
NO: 500 ppm
8% O2
2% H2O
2% CO2
N2 as balance gas
T = 150–350 °C
90 [83]
M/Ba/Al (M = Mn, Fe, Co, Ni and Cu) DBD 0–40 kV, 40 kHz, 1.8 W (in the rich phase)
phase)
NO: 500 ppm
8% O2
2% H2O
Ar as balance gas
T = 200–350 °C
100 [84]
Pt/Ba/Al
Pt particle size = 2.7 nm
Pd/Co/Ba/Al
Pd particle size = 3.1 nm
Pd/Ba/Al
Pd particle size = 3.5 nm
DBD 40 kHz, 1.8 W (in the rich phase)
NO: 500 ppm
8% O2
2% H2O
Ar as balance gas
T = 150–350 °C
99 [85]
Pt/Ba/Al
Pt particle size = 2.1 nm
Pt/Co/Ba/Al
Pt particle size = 1.6 nm
Pt/Mn/Ba/Al
Pt particle size = 1.8 nm
Pt/Cu/Ba/Al
Pt particle size = 2.1 nm
DBD 40 kHz, 1.8 W (in the rich phase)
NO: 500 ppm
8% O2
2% H2O
Ar as balance gas
T = 150–350 °C
80 [86]
Zeolites (H–ZSM-5) DBD 0.03–4 W
Reacting flow rate: 66 mL min−1
NO: 1800 ppm
10% O2
He as balance gas
1 atm, 25 °C
97.8 [87]
Cu-modified CMS DBD 7.6 kV, 8.9 kHz, 200 W
Reacting flow rate: 300 mL min−1
0.05% NO
3% O2
N2 as balance gas
96.2 [88]
In/H–BEA zeolite
In particle size = 6–10 nm
DBD 0–1.125 W
Reacting flow rate: 500 mL min−1
NO: 440 ppm
NO2: 14 ppm
CH4: 600 ppm
SO2: 0–100 ppm
6% O2
7% H2O
Ar as balance gas
T = 230–570 °C
99 [89]
MnCu/TiO2 DBD–WESP 8 kHz, 10 kV and 200 W
SO2: 0–2000 mg·m−3
NO: 200–400 mg·m−3
10% O2 and N2 balancing
Reacting flow rate: 4 L min−1
Cleaning water flow rate: 3.6 L min−1
1 atm, 25 °C
93.4 [48]
γ-Al2O3 DBD 7 W
NO: 440 ppm
NO2: 14 ppm
SO2: 460 ppm
21% O2
N2 balancing
Reacting flow rate: 600 mL min−1
1 atm, 25 °C
45 [56]
Non-Catalytic Removal Via NTP Technology
NTP Technology Operative Conditions NOx Removal Efficiency %
(Maximum Value Reached)
Reference
DBD 0–7 kV, 1–2000 Hz [90]
Volume barrier discharge (VBD) 80–500 Hz, 0.56 kW
air 30 L min−1
Methane 10 L min−1
90 [91]
DBD 40 kV, 50 Hz
NO: 100 ppm
SO2: 300 ppm
N2 as balance gas
80 [92]
DBD 16 kHz, 40 kV
Reacting flow rate: 1 L min−1
NO: 300 ppm
5% O2
N2 as balance gas
77 [93]
DBD 60 kV, 5–25 kHz
Reacting flow rate: 10 L min−1
NO: 500 ppm
C2H2: 1000 ppm
6% O2
N2 as balance gas
40 [94]
DBD 0–5 kV, 15 kHz, 45 W
Reacting flow rate: 1 L s−1
HC: 10 ppm
NOx: 116 ppm
3.32% CO2
0.5% CO
17.03% O2
95 [95]
DBD 23 kV, 20 kHz, 250 W
Reacting flow rate: 150 L min−1
NO: 350 ppmv
SO2: 800 ppmv
88.8 [96]
DBD 0–7 kV, 60 Hz
NO: 300 ppm
SO2: 0–1000 ppm
4.2% O2
N2 as balance gas
100 [97]