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. 2020 Jun 12;59(13):8916–8924. doi: 10.1021/acs.inorgchem.0c00734

Figure 3.

Figure 3

(a) Plot of the adduct [PS3Bi]2[BOT] (Bi, purple; S, yellow; P, orange; F, green; O, red; C, gray). Hydrogen atoms and solvent molecules have been omitted for clarity. (b) Side view of the section marked with asterisk in (a) showing the central core (CF3 groups are not shown). (c) ORTEP representation of the C3-symmetric [PS3Bi]3+ moiety (thermal ellipsoids are drawn at 50% probability). Hydrogen atoms, solvent molecules, and the [BOT]6– cluster have been omitted for clarity. Selected atomic distances (Å): Bi–P 2.800(3), Bi–S 2.749(9), Bi–O[triflate] 2.760(1).