Table 4. Log K* and pM Values for the Studied Systems at pH 7.4.
log K* |
||||||||||
---|---|---|---|---|---|---|---|---|---|---|
species | DP1 | species | DP2 | species | Term-DEH | species | Mid-DEH | species | Bis-DEH | |
1N | CuH2L | –1.11 | CuH2L | –1.79 | CuH2L | –1.98 | CuH2L | 0.04 | ||
2N | CuHL | –7.13 | CuHL | –6.57 | ||||||
3N | CuL | –9.75 | CuL | –6.88 | CuL | –13.5 | CuL | –12.28 | CuL | –9.62 |
4N | CuLH–1 | –14.83 | CuLH–3 | –23.02 | CuLH–1 | –22.34 | CuLH–2 | –21.05 | CuLH–1 | –15.21 |
DP1 | DP2 | Term-DEH | Mid-DEH | Bis-DEH | |
---|---|---|---|---|---|
pCu (pH 7.4)a ([L] = 1.1 × 10–3, [Cu(II)] = 10–3) | 8.34 | 8.23 | 5.58 | 5.74 | 8.23 |
pCu (pH 7.4)b ([L] = 10–5, [Cu(II)] = 10–6) | 14.65 | 14.41 | 9.11 | 9.44 | 14.43 |
pMn (pH 7.4)a ([L] = 0.55 × 10–3, [Mn(II)] = 0.5 × 10–3) | 3.54 | 3.58 | 3.69 | 4.24 | 3.81 |
pMn (7.4)b ([L] = 10–5, [Mn(II)] = 10–6) | 6.05 | 6.04 | 6.08 | 6.53 | 6.13 |
Concentrations used for potentiometric analysis.
MCT physiologically relevant conditions.