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. 2020 Mar 26;59(7):4661–4684. doi: 10.1021/acs.inorgchem.9b03737

Table 4. Log K* and pM Values for the Studied Systems at pH 7.4.

  log K*
  species DP1 species DP2 species Term-DEH species Mid-DEH species Bis-DEH
1N CuH2L –1.11     CuH2L –1.79 CuH2L –1.98 CuH2L 0.04
2N         CuHL –7.13 CuHL –6.57    
3N CuL –9.75 CuL –6.88 CuL –13.5 CuL –12.28 CuL –9.62
4N CuLH–1 –14.83 CuLH–3 –23.02 CuLH–1 –22.34 CuLH–2 –21.05 CuLH–1 –15.21
  DP1 DP2 Term-DEH Mid-DEH Bis-DEH
pCu (pH 7.4)a ([L] = 1.1 × 10–3, [Cu(II)] = 10–3) 8.34 8.23 5.58 5.74 8.23
pCu (pH 7.4)b ([L] = 10–5, [Cu(II)] = 10–6) 14.65 14.41 9.11 9.44 14.43
pMn (pH 7.4)a ([L] = 0.55 × 10–3, [Mn(II)] = 0.5 × 10–3) 3.54 3.58 3.69 4.24 3.81
pMn (7.4)b ([L] = 10–5, [Mn(II)] = 10–6) 6.05 6.04 6.08 6.53 6.13
a

Concentrations used for potentiometric analysis.

b

MCT physiologically relevant conditions.