Table 1. Structural Parameters Derived from the DSC and SAXS Data for UHMWPE and HDPE Samplesa.
sample | heat of melting [J/g] | DSC weight crystallinity, Xc [%] | DSC mean crystal thickness lcb, [nm] | crystal thickness estimated from the melting <keep-together>peak—lc′c [nm]</keep-together> | lc + la[nm]d | <keep-together>lc′ + la</keep-together> [nm]d | long period from SAXS [nm] |
---|---|---|---|---|---|---|---|
HDPE 06 | 194.2 | 66.3 | 22.46 | 28.14 | 35.81 | 44.84 | 34.6 |
UHMWPE 5 | 153.9 | 52.5 | 18.27 | 22.4 | 37.6 | 46.1 | 40.6 |
UHMWPE 9 | 154.3 | 52.7 | 18.61 | 23.34 | 38.14 | 47.8 | 43.6 |
Mean crystal thickness obtained from the crystal thickness distributions in Figure 4, amorphous layer thickness calculated from the crystallinity degree and the crystal thickness. Assuming PE crystal density 1.0 g/cm354 and density of the PE amorphous phase 0.855 g/cm3.55 LP determined from the SAXS images in Figure 5.