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. 2020 Jul 17;53(14):6063–6077. doi: 10.1021/acs.macromol.9b02154

Table 1. Structural Parameters Derived from the DSC and SAXS Data for UHMWPE and HDPE Samplesa.

sample heat of melting [J/g] DSC weight crystallinity, Xc [%] DSC mean crystal thickness lcb, [nm] crystal thickness estimated from the melting <keep-together>peak—lcc [nm]</keep-together> lc + la[nm]d <keep-together>lc + la</keep-together> [nm]d long period from SAXS [nm]
HDPE 06 194.2 66.3 22.46 28.14 35.81 44.84 34.6
UHMWPE 5 153.9 52.5 18.27 22.4 37.6 46.1 40.6
UHMWPE 9 154.3 52.7 18.61 23.34 38.14 47.8 43.6
a

Mean crystal thickness obtained from the crystal thickness distributions in Figure 4, amorphous layer thickness calculated from the crystallinity degree and the crystal thickness. Assuming PE crystal density 1.0 g/cm354 and density of the PE amorphous phase 0.855 g/cm3.55 LP determined from the SAXS images in Figure 5.

b

Calculated from the lamellae thickness distribution obtained from the DSC melting curve using eqs 5 and 6.

c

Calculated from the maximum of the melting peak with eq 5.

d

la and la were calculated from lc or lc, respectively, and Xc using eqs 7 and 8.