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. 2020 Jul 17;53(14):6063–6077. doi: 10.1021/acs.macromol.9b02154

Table 3. Parameters Derived from Fitting the Experimental Curves with Gaussian and Non-Gaussian/8-Chain Models: the Yield Stress Y, Strain-Hardening Modulus Gn, Network Stretch Limit λMax, and the Effective Cross-Link Density, Ne.

  Gaussian model (eq 9)a
non-Gaussian/8-chain model (eq 10)b
  Y (MPa) Gn (MPa) Y (MPa) λmax = n1/2 Gn (MPa) Ne = Gn/kT (×10–26 m–3)
HDPE 6 41.4 2.17 39.0 2.98 2.68 6.5
UHMWPE 5 36.8 4.43 34.3 2.84 4.45 10.8
UHMWPE 9 34.3 6.00 31.7 2.58 5.41 13.1
a

Fitting range: e = 0.35–0.72, (λ2 – 1/λ2 = 1.5 – 4).

b

Fitting range: e = 0.35–1.40, (λ2 – 1/λ2 = 1.5 – 16).