Fig. 5. Synthetic diagram of photo-immunoconjugate nanoparticles (PIC-NPs).
a The illustration of PIC synthesis by conjugation of BPD derivative photosensitizers to PEGylated cetuximab via carbodiimide crosslinker chemistry. b showing the various stoichiometry of BPD reacted with cetuximab species. c Transmission electron microscopy (TEM) image of poly (ethylene glycol)-poly(lactic-co-glycolic acid) (PEG-PLGA) polymeric nanoparticles prepared via nanoprecipitation method. Scale bar 100 nm. d Schematic representation of PIC-NP synthesis via copper-free click chemistry. Azide-containing FKR560 dye-loaded PLGA nanoparticles were reacted with the dibenzocyclooctyne (DBCO)-containing PICs to form PIC-NPs. e Covalent conjugation of PICs onto 80 nm PEG-PLGA NPs resulted in the formation of monodispersed PIC-NPs around 100 nm in diameter. Adapted with permission from [140]. Copyright 2018 WILEY‐VCH Verlag GmbH & Co