Figure 3.
Allylic functionalization scope studies. Reactions conducted using 0.5 mmol 1, 2.5 mmol 2, 1 mol% [Ir(ppy)2(dMeObpy)]PF6, 15 mol% Y(OTf)3, 30 mol% 5-Cl-phen, and 7.5 mL toluene and irradiated with a 16 W LED lamp (465 nm) for 16 h unless otherwise noted. Values in parentheses represent the ratio of regioisomers. a Reaction conducted for 32 h. b Reaction conducted for 24 h. c Reaction conducted using 1 mol% [Ir(Fppy)2(dtbbpy)]PF6.