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. 2020 Jul 29;12(8):482. doi: 10.3390/toxins12080482

Figure 3.

Figure 3

Schematic view of degradation of two hydrazinic toxins, Gyromitrin and Agaritine, into instablediazonium ions (from which reactive radicals are generated): (A) Gyromitrin: (acetaldehyde methylformylhydrazone)→N-methyl-N-formylhydrazine (MFH)→monomethylhydrazine (=MH or MMH). (B) Agaritine: (β-N-[γ-L-(+)- glutamyl]-4-hydroxymethylphenylhydrazine) →4-(hydroxymethyl)phenylhydrazine (HMPH)→ 4- (hydroxymethyl)benzenediazonium ion (HMBD).