Table 2.
Bond lengths [Å] and angles [deg.] for 1 and 3.
| [(η6-p-cymene)RuCl(py2CO)]PF6 (1) | |||||
| Ru(1)–N(1) | 2.1022(14) | N(1)–Ru(1)–N(2) | 84.54(6) | – | – |
| Ru(1)–N(2) | 2.0950(14) | N(1)–Ru(1)–Cl(1) | 86.44(4) | – | – |
| Ru(1)–Cl(1) | 2.3942(4) | N(2)–Ru(1)–Cl(1) | 85.83(4) | – | – |
| Ru(1)···Cg | 1.6841(12) | – | – | – | – |
| NH4[IrCl4(py2CO)]·H2O (3) | |||||
| Ir(1)–N(1) | 1.998(7) | N(1)–Ir(1)–O(1) | 79.2(2) | Cl(3)–Ir(1)–Cl(2) | 89.94(8) |
| Ir(1)–O(1) | 2.053(6) | N(1)–Ir(1)–Cl(3) | 97.0(2) | Cl(1)–Ir(1)–Cl(2) | 90.49(11) |
| Ir(1)–Cl(1) | 2.354(2) | O(1)–Ir(1)–Cl(3) | 175.61(15) | N(1)–Ir(1)–Cl(4) | 90.4(2) |
| Ir(1)–Cl(2) | 2.349(2) | N(1)–Ir(1)–Cl(1) | 89.1(2) | O(1)–Ir(1)–Cl(4) | 87.62(17) |
| Ir(1)–Cl(3) | 2.329(2) | O(1)–Ir(1)–Cl(1) | 92.35(17) | Cl(3)–Ir(1)–Cl(4) | 90.26(8) |
| Ir(1)–Cl(4) | 2.354(2) | Cl(3)–Ir(1)–Cl(1) | 89.74(8) | Cl(1)–Ir(1)–Cl(4) | 179.56(6) |
| – | – | N(1)–Ir(1)–Cl(2) | 173.07(19) | Cl(2)–Ir(1)–Cl(4) | 89.63(8) |
| – | – | O(1)–Ir(1)–Cl(2) | 93.88(17) | – | – |