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(A) Formation of [CoIII(DPP3–)(NH2tBu)2] and [CoIII(DPP3–)(NH2Ad)2]. Ad = 1-adamantyl. (B) Displacement ellipsoid plot (50% probability level) of [CoIII(DPP3–)(NH2Ad)2]. (C) Displacement ellipsoid plot (50% probability level) of [CoIII(DPP3–)(NH2tBu)2]. H atoms and disorder are omitted for clarity.
