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. Author manuscript; available in PMC: 2021 Apr 6.
Published in final edited form as: Angew Chem Int Ed Engl. 2020 Jan 16;59(15):5880–5889. doi: 10.1002/anie.201907662

Figure 1.

Figure 1.

(a) Photochemical pathways for TPDs. The adjacent aryl and trifluoromethyl groups (−CF3) stabilize the diazo intermediate and avoid side rearrangement reaction. (b-d) Three strategies involving diazirines structural optimization for TPDs based probes.