Table 2:
Typical parameters for a 1H-13C cross-polarization experiment.
MAS rate: 25 kHz (rotor period, τr = 40 μs) | |||
---|---|---|---|
Pulse | Power (kHz) |
Duration (μs) | Phase |
pH,1(π/2) | 110 | 2.27 | y,−y |
pH,2 | Linear ramp: 50 to 100 | 2,000 | x |
pC,1 | 50 | 2000 | x,x,y,y,−x,−x,−y,−y |
pC,2 | 0* | 5 | y,y,−x,−x,−y,−y,x,x |
ϕReceiver | x,−x,y,−y,−x,x,−y,y | ||
Delay | Duration | ||
d1 | 2 s |
Decoupling period |
Power (kHz) | Method |
---|---|---|
dec1 | 100 | TPPM |
comments | *zero except during calibration |