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. Author manuscript; available in PMC: 2021 Jun 24.
Published in final edited form as: Chem Rev. 2020 Mar 4;120(12):5107–5157. doi: 10.1021/acs.chemrev.9b00704

Figure 21.

Figure 21.

A modified Lowe-Thorneley scheme for N2 reduction in Mo-nitrogenase based on work from refs 188 and 197. The En notation refers to the n number of proton and electron equivalents loaded on to one αβ-dimer of NifDK. The resting state of the cycle is E0 and the release of H2 and NH3 during the cycle is indicated.