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. 2019 Feb 5;9(3):2400–2406. doi: 10.1021/acscatal.9b00118

Table 3. Iridium-Catalyzed Olefin Migration/Cope Rearrangement of Alkenyl Cyclopropanol Ethersa.

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a

Reaction conditions: ω-Ene alkenylcyclopropanol derivative (0.5 mmol), [Ir(COD)Cl]2 (1.0 mol %), PCy3 (6.0 mol %), NaBArF4 (2.5 mol %), 1,2-DCE (1.0 mL), 85 °C.

b

Yield of isolated product after purification by flash chromatography.

c

Inseparable mixture of olefin isomers.