Table 3.
Intra-day and inter-day precision and accuracy for the determination of AZI and LEVO mixtures using the proposed spectrophotometric methods.
Concentration (μg/mL) |
Method | Recovery % ± SDa |
RSD%b |
Er%c |
||||
---|---|---|---|---|---|---|---|---|
AZI | LEVO | AZI | LEVO | AZI | LEVO | AZI | LEVO | |
(a) Accuracy and intra-day precision | ||||||||
10 | 20 | Direct | 101.05 ± 0.59 | 100.95 ± 0.26 | 0.58 | 0.25 | 1.05 | 0.95 |
D1 | 100.53 ± 1.75 | 100.32 ± 0.69 | 1.75 | 0.69 | 0.53 | 0.32 | ||
40 | 10 | Direct | 100.75 ± 0.81 | 100.79 ± 0.12 | 0.79 | 0.12 | 0.75 | 0.97 |
D1 | 99.99 ± 0.91 | 100.32 ± 0.69 | 0.91 | 0.69 | -0.01 | 0.32 | ||
20 | 20 | Direct | 99.69 ± 0.44 | 100.76 ± 0.91 | 0.44 | 0.91 | -0.31 | 0.76 |
D1 |
100.85 ± 0.51 |
101.58 ± 0.91 |
0.51 |
0.90 |
0.85 |
1.58 |
||
(b) Accuracy and inter-day precision | ||||||||
10 | 20 | Direct | 101.44 ± 0.89 | 100.89 ± 0.36 | 0.88 | 0.35 | 1.44 | 0.87 |
D1 | 99.36 ± 1.01 | 99.92 ± 0.53 | 1.02 | 0.53 | -0.64 | -0.08 | ||
40 | 10 | Direct | 100.02 ± 0.22 | 100.83 ± 0.33 | 0.22 | 0.33 | 0.02 | 0.83 |
D1 | 100.57 ± 1.16 | 100.25 ± 0.64 | 1.15 | 0.64 | 0.57 | 0.25 | ||
20 | 20 | Direct | 101.53 ± 1.12 | 98.70 ± 0.69 | 1.09 | 0.69 | 1.53 | -1.29 |
D1 | 101.14 ± 0.88 | 101.27 ± 1.13 | 0.87 | 1.12 | 1.14 | 1.27 |
(a) is standard deviation, (b) is percentage relative standard deviation and (c) is percentage error.