Table 2. Total Amounts of Mb Adsorbed, and Melting Temperatures and Heats of Fusion of Pore Water Obtained for SBA53a.
| system | [Mb]e/mg mL–1 | Atotf/g g–1 | Tmg/°C | ΔHh/J g–1 |
|---|---|---|---|---|
| W/Wb | 0 | –22.4 | –47 | |
| PB/PBc | 0 | –24.2 | –33 | |
| PB/Wd | 0 | –22.2 | –50 | |
| W/Wb | 1.5 | 0.056 | –22.9 | –34 |
| PB/PBc | 1.5 | 0.052 | –25.6 | –34 |
| PB/Wd | 1.5 | 0.055 | –23.5 | –36 |
a
The experimental scheme for each system is shown in Figure S6.
b
Pure water was used for shaking, rinsing, and the DSC experiment.
c
Phosphate buffer solution was used for shaking, rinsing, and the DSC experiment.
d
Phosphate buffer solution was used for shaking, and pure water was used for rinsing and the DSC experiment.
e
Initial concentration of Mb in the phosphate buffer or pure water used for shaking.
f
Total amount of adsorbed Mb (per gram of mesoporous silica) derived from the adsorption assay.
g
Onset melting temperature of pore water.
h
Heat of fusion of pore water.