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. 2020 Sep 1;5(36):23334–23342. doi: 10.1021/acsomega.0c03184

Table 1. Optical and Electrochemical Characterization of AZO-III and AZO-IV.

  λmax Abs/Emi (nm)
        
HTMs DCM film HOMO (eV) LUMO (eV) bEg (eV) dEg (eV)
AZO-III 409/565 412/567 –4.97a, −4.93b –2.41c, −1.64b 3.29b 2.56d
AZO-IV 412/565 417/576 –4.99a, −4.91b –2.45c, −1.64b 3.27b 2.54d
a

HOMO level determined by DPV.

b

Energy levels and bEg determined by NBO analysis.

c

LUMO level by using optical band gap.

d

Optical bandgap.