Table 1. Decomposition Enthalpies (millielectronvolts per atom) Computed at the DFT/PBESol Level of Theory.
decomposition mechanism | ΔHd (meV/atom) |
---|---|
Cs3Cu4In2Cl13 → 4CuCl + 2InCl3 + 3CsCl | 83.2 |
Cs3Cu4In2Cl13 → Cs3Cu2Cl5 + 2InCl3 + 2CuCl | 57.5 |
Cs3Cu4In2Cl13 → Cs3In2Cl9 + 4CuCl | 23.5 |