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. 2020 Jul 1;68(29):7734–7744. doi: 10.1021/acs.jafc.0c02842

Table 2. Quantification of Nonanthocyanin Phenolic Compounds in White (WB) and Blue Bilberry (BB) Juices and Winesa.

    content (mg/L)
t-testb
peak compound WB juice WB wine BB juice BB wine WB juice vs BB juice WB juice vs WB wine BB juice vs BB wine
phenolic acids
1 5-caffeoylquinic acid 8.12 ± 0.05 11.27 ± 0.17 4.34 ± 0.20 4.38 ± 0.14 *** ***  
2 protocatechuic acid hexoside 0.38 ± 0.01 1.23 ± 0.31 0.90 ± 0.08 0.71 ± 0.02 *** * **
3 p-coumaric acid derivative-1 1.11 ± 0.02 1.15 ± 0.04 2.59 ± 0.19 2.65 ± 0.09 ***    
4 p-coumaric acid derivative-2 0.06 ± 0.00 0.04 ± 0.01 0.24 ± 0.08 0.21 ± 0.15 *    
5 caffeic acid hexoside-1 16.37 ± 0.12 0.16 ± 0.02 22.93 ± 0.64 5.09 ± 0.20 *** *** ***
6 3-caffeoylquinic acid 3.39 ± 0.09 2.71 ± 0.08 6.74 ± 0.23 4.41 ± 0.20 *** *** ***
7 4-caffeoylquinic acid 0.03 ± 0.03 0.06 ± 0.00 0.30 ± 0.05 0.43 ± 0.11 ***    
8 caffeic acid 0.74 ± 0.01 17.21 ± 0.33 0.55 ± 0.13 17.48 ± 0.54   *** ***
9 caffeic acid hexoside-2 2.76 ± 0.06 3.05 ± 0.07 1.95 ± 0.10 2.07 ± 0.26 *** ***  
10 caffeoylquinic acid isomer 0.37 ± 0.02 0.43 ± 0.20 0.32 ± 0.04 0.24 ± 0.03 *   *
11 p-coumaroylquinic acid 0.07 ± 0.01 0.09 ± 0.03      
12 p-coumaric acid 2.28 ± 0.06 3.56 ± 0.13 4.26 ± 0.15 5.57 ± 0.14 *** *** ***
13 dicaffeoylquinic acid-1 0.56 ± 0.32 0.52 ± 0.17      
14 dicaffeoylquinic acid-2 0.99 ± 0.24 1.08 ± 0.13      
15 caffeic acid derivative hexoside 1.07 ± 0.02 1.12 ± 0.04 0.94 ± 0.11 0.93 ± 0.03      
16 p-coumaroyl monotropein-1 12.83 ± 0.13 14.65 ± 0.30 10.65 ± 0.66 10.91 ± 0.44 *** ***  
17 p-coumaroyl monotropein-2 14.98 ± 0.18 24.95 ± 0.37 58.82 ± 1.44 53.53 ± 1.57 *** *** **
18 p-coumaric acid derivative 0.24 ± 0.01 1.28 ± 0.03 0.52 ± 0.03 0.55 ± 0.06 *** ***  
19 p-coumaric acid derivative-a 1.21 ± 0.01 2.10 ± 0.04 4.88 ± 0.11 4.93 ± 0.13 *** ***  
20 p-coumaric acid derivative-b 0.98 ± 0.01 1.54 ± 0.02 1.29 ± 0.14 1.37 ± 0.04 * ***  
21 p-coumaric acid derivative-c 0.04 ± 0.01 0.31 ± 0.03 0.65 ± 0.03 0.75 ± 0.04 *** *** *
22 caffeic acid derivative 0.30 ± 0.01 0.70 ± 0.01 1.87 ± 0.06 1.71 ± 0.06 *** *** *
  total phenolic acids 67.34 ± 0.86 87.62 ± 2.22 126.29 ± 5.03 119.51 ± 4.55 *** *** *
flavonols
23 myricetin 3-O-galactoside 0.29 ± 0.01 0.31 ± 0.04 2.36 ± 0.10 2.39 ± 0.07 ***    
24 myricetin 3-O-glucoside 1.48 ± 0.04 1.94 ± 0.46 4.00 ± 0.69     **
25 quercetin 3-O-galactoside 4.48 ± 0.12 5.01 ± 0.07 8.20 ± 0.34 8.06 ± 0.34 *** ***  
26 quercetin 3-O-glucuronide 5.17 ± 0.10 5.76 ± 0.12 6.38 ± 0.18 5.93 ± 0.13 *** *** **
27 quercetin 3-O-glucoside 0.25 ± 0.02 0.33 ± 0.01 1.43 ± 0.10 1.41 ± 0.04 *** ***  
28 laricitrin 3-O-galactoside 0.22 ± 0.02 0.18 ± 0.00     *
29 laricitrin 3-O-glucoside 0.26 ± 0.01 0.31 ± 0.01 2.34 ± 0.05 2.33 ± 0.08 *** **  
30 quercetin 3-O-arabinoside 0.25 ± 0.02 0.26 ± 0.03 0.92 ± 0.06 0.90 ± 0.06 ***    
31 quercetin 3-O-xyloside 0.27 ± 0.02 0.36 ± 0.01 0.52 ± 0.03 0.47 ± 0.02 *** **  
32 myricetin aglycone 0.32 ± 0.01 0.44 ± 0.01 0.60 ± 0.03 0.67 ± 0.03 *** *** **
33 isorhamnetin 3-O-galactoside 0.46 ± 0.12 0.44 ± 0.12      
34 syringetin 3-O-galactoside 0.23 ± 0.01 0.47 ± 0.01 0.90 ± 0.03 0.84 ± 0.04 *** ***  
35 syringetin 3-O-glucoside 0.37 ± 0.00 0.34 ± 0.01 2.28 ± 0.07 2.40 ± 0.06 ***    
36 quercetin aglycone 0.19 ± 0.00 0.31 ± 0.00 0.40 ± 0.02 0.42 ± 0.01 *** ***  
37 syringetin aglycone 0.22 ± 0.00 0.21 ± 0.01 0.28 ± 0.02     ***
  total flavonols 12.07 ± 0.15 15.58 ± 0.20 29.15 ± 0.7 30.72 ± 0.84 *** *** *
flavan-3-ols
38 (−)-epigallocatechin 0.21 ± 0.01 0.37 ± 0.25 0.25 ± 0.04 0.31 ± 0.06      
39 (+)-catechin 1.48 ± 0.18 1.26 ± 0.02     *
40 procyanidin B-type dimer 1.86 ± 0.13 1.47 ± 0.36 3.27 ± 0.39 4.05 ± 0.72 **    
41 (−)-epicatechin 1.96 ± 0.14 0.90 ± 0.41 2.56 ± 0.10 1.63 ± 0.19 *** ** ***
42 procyanidin B-type trimer 0.21 ± 0.02 0.39 ± 0.20 1.13 ± 0.13 0.80 ± 0.08 ***   **
  total flavan-3-ols 4.24 ± 0.26 3.14 ± 0.36 8.69 ± 0.35 8.04 ± 0.59 *** **  
a

–: not detected.

b

Independent-samples t-test. *, **, and ***: significant at p < 0.05, p < 0.01, and p < 0.001, respectively.