Table 1.
Complex | E1/2 [V] [ΔE, (Ipc/Ipa)]a | λmax [nm] (ε [103 M−1 cm−1]) |
---|---|---|
1 | 0.10 [0.70, 1]; 0.50 [0.70, 1] | 461 (54) |
2 | − 0.06 [0.80, 1]; 0.27 [0.70, 1] | 500 (47) |
3 | − 0.30 [0.70, 1]; 0.30 [0.70, 1] | 514 (23) |
4 | − 0.05 [0.60, 1]; 0.25 [0.70, 1]; 0.50 [0.80, 1] | 481 (15) |
Measured in CH2Cl2. (vs. FeCp/FeCp+).
aPt disc working, Pt wire auxiliary, Ag reference electrode; ferrocene/ferrocenium redox couple as internal reference, CH2Cl2 containing 0.1 M [n-Bu4N][PF6], 20 °C, scan rate 100 mV s-1 at 5.10–4 M.