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. 2020 Sep 17;10:15292. doi: 10.1038/s41598-020-71769-2

Table 1.

Cyclic voltammetry and linear optical data.

Complex E1/2 [V] [ΔE, (Ipc/Ipa)]a λmax [nm] (ε [103 M−1 cm−1])
1 0.10 [0.70, 1]; 0.50 [0.70, 1] 461 (54)
2 − 0.06 [0.80, 1]; 0.27 [0.70, 1] 500 (47)
3 − 0.30 [0.70, 1]; 0.30 [0.70, 1] 514 (23)
4 − 0.05 [0.60, 1]; 0.25 [0.70, 1]; 0.50 [0.80, 1] 481 (15)

Measured in CH2Cl2. (vs. FeCp/FeCp+).

aPt disc working, Pt wire auxiliary, Ag reference electrode; ferrocene/ferrocenium redox couple as internal reference, CH2Cl2 containing 0.1 M [n-Bu4N][PF6], 20 °C, scan rate 100 mV s-1 at 5.10–4 M.