Table 1.
Summary of MOF that synthesized with ambient temperature (RT) and ambient pressure (1 atm) process.
| MOF | Metal source | Ligand | Modulator | Solvent | Time | STY (kg m−3 day−1) | Yield (g) | Yield (%) | Surface area (m2 g−1) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|
| MOF-5 | Zinc acetate dihydrate | Terephthalic acid | TEA | DMF | 2.5 h | – | 4.92 | 63 | 3909 | [41] |
| MOF-5 | Zinc acetate dihydrate | Terephthalic acid | – | DMF | 45 min | – | – | – | – | [41] |
| MOF-74 | Zinc acetate dihydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 18 h | – | 0.27 | 69 | 1187 | [41] |
| MOF-177 | Zinc acetate dihydrate | Benzenetribenzoic acid | – | DEF | 3 h | – | 0.49 | 60 | 4944 | [41] |
| HKUST-1* | Copper acetate monohydrate | 1,3,5-Benzenetricarboxylic acid | TEA | DMF/EtOH/water | 23 h | – | 0.32 | 44 | – | [41] |
| IRMOF-0 | Zinc acetate dihydrate | Acetylenedicarboxylic acid | TEA | DMF | overnight | – | – | – | – | [41] |
| HKUST-1 | Copper(II) acetate monohydrate | 1,3,5-Benzenetricarboxylic acid | – | water | 1 h | 2035 | – | 84.8 | 1763 | [63] |
| HKUST-1 | Copper(II) nitrate hemi(pentahydrate) | 1,3,5-Benzenetricarboxylic acid | – | water | 1 h | 41 | – | 34.2 | 1403 | [63] |
| ZIF-8 | Zinc nitrate hexahydrate | 2-Methylimidazole | TEA | water | 30 min | – | – | 90 | 491.54 | [64] |
| MIL-53(Al) | Aluminum nitrate nanohydrate | Disodium terephthalate | – | water | 4 h-7d | – | – | – | 1048 | [65] |
| MIL-53(Al) | Aluminum nitrate nanohydrate | Terephthalic acid | NaOH | water | 24 h | – | – | – | 1072 | [65] |
| NH2-MIL-53(Al) | Aluminum chloride hexahydrate | 2-Aminoterephthalic acid | NaOH | water | 24 h | – | – | – | – | [65] |
| NO2-MIL-53(Al) | Aluminum nitrate nanohydrate | 2-Nitroterephthalic acid | NaOH | water | 24 h | – | – | – | – | [65] |
| MOF-74(Zn) | Zinc acetate dihydrate | 2,5-Dihydroxyterephtalic acid | NaOH | water | 24 h | – | – | – | – | [65] |
| MOF-5 | Zinc nitrate hexahydrate | Disodium terephthalate | – | DMF | 24 h | – | – | – | – | [65] |
| MOF-74(Zn) | Zinc acetate dihydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 20 h | – | – | – | 867 | [67] |
| MOF-74(Ni) | Nickel acetate tetrahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 20 h | – | – | – | 402 | [67] |
| MOF-74(Co) | Cobalt acetate tetrahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 20 h | – | – | – | 521 | [67] |
| MOF-74(Mn) | Manganese acetate tetrahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 20 h | – | – | – | 491 | [67] |
| MOF-74(Mg) | Magnesium acetate tetrahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF | 20 h | – | – | – | 1007 | [67] |
*MOF-199.