Table 2.
Summary of MOF that synthesized with high-temperature (>RT) and ambient pressure (1 atm) process.
| MOF | Metal source | Ligand | Modulator | Solvent | Time | Temperature (℃) | STY (kg m−3 day−1) | Yield (g) | Yield (%) | Surface area (m2 g−1) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Al-fum*, a | Aluminum sulfate octadecahydrate | Fumaric acid | NaOH | water | 10 min | RT | 4742 | 26.2 | 76% | 723 | [68] |
| Al-fum* | Aluminum sulfate octadecahydrate | Fumaric acid | NaOH | water | 10 min | 60 | 5339 | 29.5 | 86% | 1140 | [68] |
| MOF-74(Ni) | Nickel acetate tetrahydrate | 2,5-Dihydroxyterephtalic acid | – | water | 1 h | 160 (reflux) | 680 | 17.9 | 91.60% | 1233 | [42] |
| MOF-74(Mg) | Magnesium nitrate hexahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF/EtOH/water | 24 h | 120 (reflux) | – | 7.6 | – | 984 | [73] |
| MOF-174(Mg) | Magnesium nitrate hexahydrate | 4-(4-carboxy-3-hydroxy-phenyl)-2-hydroxy-benzoic acid | – | DMF/EtOH/water | 12 h | 120 (reflux) | – | 3.82 | – | 2465 | [73] |
| MOF-184(Mg) | Magnesium nitrate hexahydrate | 4-[2-(4-carboxy-3-hydroxy-phenyl)ethynyl]-2-hydroxy-benzoic acid | – | DMF/EtOH/water | 24 h | 120 (reflux) | – | 0.78 | – | 3154 | [73] |
| MOF-74(Ni) | Zinc nitrate hexahydrate | 2,5-Dihydroxyterephtalic acid | – | DMF/EtOH/water | 24 h | 120 (reflux) | – | 46.4 | – | 1176 | [73] |
| MOF-174(Ni) | Zinc nitrate hexahydrate | 4-(4-carboxy-3-hydroxy-phenyl)-2-hydroxy-benzoic acid | – | DMF/EtOH/water | 12 h | 120 (reflux) | – | 2.82 | – | 1444 | [73] |
| MOF-184(Ni) | Zinc nitrate hexahydrate | 4-[2-(4-carboxy-3-hydroxy-phenyl)ethynyl]-2-hydroxy-benzoic acid | – | DMF/EtOH/water | 12 h | 120 (reflux) | – | 1.95 | – | 2449 | [73] |
| UiO-66 | Zirconyl chloride octahydrate | Terephthalic acid | Formic acid | DMF | 2 h | 140 (reflux) | – | 100 | – | 604 | [71] |
| MOF-801 | Zirconyl chloride octahydrate | Fumaric acid | Formic acid | DMF | 2 h | 140 (reflux) | – | 100 | – | 838 | [71] |
| UiO-66-NH2 | Zirconium chloride | 2-Aminoterephthalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | 23.59 | 90.70% | 1075 | [69] |
| UiO-66 | Zirconium chloride | Terephthalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 995 | [69] |
| UiO-66-(OH)2 | Zirconium chloride | 2,5-Dihydroxyterephtalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 575 | [69] |
| UiO-66–2,6-NDC | Zirconium chloride | 2,6-naphthalenedicarboxylic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 781 | [69] |
| UiO-67 | Zirconium chloride | Biphenyl-4,4′-dicarboxylic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 2087 | [69] |
| BUT-12 | Zirconium chloride | H3CTTA** | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 1254 | [69] |
| PCN-222-Ni | Zirconium chloride | Tetrakis(4-carboxyphenyl)porphyrin-Ni | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | 1724 | [69] |
| PCN-222-Co | Zirconium chloride | Tetrakis(4-carboxyphenyl)porphyrin-Co | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| Hf-UiO-66 | Hafnium tetrachloride | Terephthalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| Hf-UiO-66-NH2 | Hafnium tetrachloride | 2-Aminoterephthalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| Hf-UiO-66-(OH)2 | Hafnium tetrachloride | 2,5-Dihydroxyterephtalic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| Hf-UiO-66–2,6-NDC | Hafnium tetrachloride | 2,6-naphthalenedicarboxylic acid | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| Hf-BUT-12 | Hafnium tetrachloride | H3CTTA | Acetic acid/water | DMF | 15 min | 120 (reflux) | – | – | – | – | [69] |
| CAU-10-H | Aluminum sulfate | Sodium isophthalate | NaOH | water | 3 h | reflux | – | – | – | – | [74] |
| CAU-10-H | Aluminum sulfate | Sodium isophthalate | Sodium aluminate | EtOH | 10 h | reflux | – | 500 | 93% | – | [74] |
*Basolite A520, **5′-(4-carboxyphenyl)-2′,4′,6′-trimethyl-[1,1′:3′,1″-terphenyl]-4,4″-dicarboxylic acid), a Control condition of Al-fum.