Table 5.
Summary of microwave heating synthesized MOF.
| MOF | Metal source | Ligand | Modulator | Solvent | Instrument | Reactor | Time | Power (W) | Temperature (°C) | STY (kg m−3 day−1) | Yield (g) | Yield (%) | Surface area (m2 g−1) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| UiO-66 | Zirconium chloride | Terephthalic acid | Acetic acid | DMF | Multi-mode microwave synthesizer | PTFE vial | 18 min | 100 | 120 | 2241 | 2.72 | 78 | 1206 | [84] |
| Cu-BDC | Copper(II) nitrate trihydrate | Terephthalic acid | – | DMF | Domestic microwave | – | 30–90 min | 300/100 | – | – | – | – | 624 | [85] |
| HKUST-1 | Copper(II) nitrate trihydrate | Trimesic acid | – | Water/DMF/EtOH | 900 W magnetron | Teflon pot | 10 min | 360 | 70 | – | 0.27 | 50 | 1185 | [86] |
| MIL-53(Fe) | Iron(III) chloride hexahydrate | Terephthalic acid | – | DMF | Mars-5, CEM | – | 2 h | – | 60–70 | – | – | – | – | [87] |
| MIL-101(Cr) | Chromium(III) nitrate nonahydrate | Terephthalic acid | HF | Water | Mars-5, CEM | Teflon autoclave | 1–60 min | 600 | 210 | – | – | – | 3891 | [88] |
| MIL-53(Al) | Aluminum chloride hexahydrate | Terephthalic acid | – | Water | Mars-5, CEM | Teflon autoclave | 5.5 h | 1200 | 150 | – | – | – | 1282 | [89] |
| MIL-53(Cr) | Chromium(III) chloride hexahydrate | Terephthalic acid | – | Water | Mars-5, CEM | Teflon autoclave | 7 h | 1200 | 175 | – | – | – | 1419 | [89] |
| MIL-47(V) | Vanadium(III) chloride | Terephthalic acid | – | Water | Mars-5, CEM | Teflon autoclave | 3 h | 1200 | 135 | – | – | – | 1049 | [89] |
| MIL-88A | Iron(III) chloride hexahydrate | Fumaric acid | – | Water | Mars-5, CEM | Stirring | 2–10 min | 600 | 80 | – | – | – | – | [90] |
| MOF-5 | Zinc nitrate tetrahydrate | Terephthalic acid | – | NMP | MDS-2100. CEM | Teflon autoclave | 15–30 min | 600 | 105 | – | – | – | 2798 | [91] |
| MOF-5 | Zinc nitrate hexahydrate | Terephthalic acid | Water | DMF | – | Teflon pot | 210 s | – | 80 | – | 0.123 | 47 | 2489 | [92] |
| IRMOF-1 | Zinc nitrate hexahydrate | Terephthalic acid | – | DEF | 520A, Resonance Instrument Inc. | Pyrex vial | 25 s | 150 | – | – | – | – | – | [93] |
| IRMOF-2 | Zinc nitrate hexahydrate | 2-Bromoterephthalic acid | – | DEF | 520A, Resonance Instrument Inc. | Pyrex vial | 40 s | 150 | – | – | – | – | – | [93] |
| IRMOF-3 | Zinc nitrate hexahydrate | 2-Aminoterephthalic acid | – | DEF/EtOH | 520A, Resonance Instrument Inc. | Pyrex vial | 35 s | 150 | – | – | [93] | |||
| MOF-74(Ni) | Nickel nitrate hydrate | 2,5-dihydroxyterephthalic acid | – | DMF/EtOH/Water | Multiwave 3000/Synthos 3000, Anton Paar | Teflon autoclave | 90 min | – | 100 | – | – | – | 1252 | [94] |
| MOF-74(Mg) | Magnesium nitrate hydrate | 2,5-dihydroxyterephthalic acid | – | DMF/EtOH/Water | – | Teflon autoclave | 90 min | – | 125 | – | – | – | 1416 | [94] |
| MIL-101(Cr) | Chromium(III) chloride hexahydrate | Terephthalic acid | NaOH | Water | MDS-2002A | Teflon autoclave | 3 min | – | 210 | – | – | – | 3208 | [95] |