Table 6.
MOF | Metal source | Ligand | Modulator | Solvent | Instrument | Max power | Power | Time | Temperature (°C) | STY (kg m−3 day−1) | Yield (%) | Surface area (m2 g−1) | Ref |
---|---|---|---|---|---|---|---|---|---|---|---|---|---|
ZIF-8 | Zinc nitrate hexahydrate | 2-methylimidazole | TEA, NaOH | DMF | Probe (VCX 500) | 500 W, 20 kHz | 60% | 1 h | – | 2140 | 85 | 1174 | [97] |
MIL-53(Fe) | Ferric chloride hexahydrate | Terephthalic acid | – | DMF | Probe (VCX 750) | – | 25–40% | 0.58–1.5 h | 50–80 | – | – | – | [87] |
MIL-53(Fe) | Ferric chloride hexahydrate | Terephthalic acid | – | DMF | Probe (VCX 500) | 500 W, 20 kHz | 60% | 15 min | – | – | 30.2 | – | [98] |
Zn-HKUST-1 | Zinc acetate dihydrate | Trimesic acid | – | DMF | – | – | 305 W, 40 kHz | 30 min | – | – | – | – | [99] |
TMU-4 | Zinc nitrate hexahydrate | 4,4′-Oxybis(benzoic acid) 4-BPDB* | TEA | DMF | Bath (SONICA-2200 EP) | 40 kHz | 40 kHz | 30–90 min | – | – | 88 | – | [100] |
CPO-27(Zn) | Zinc nitrate hexahydrate | 2,5-dihydroxyterephthalic acid | Water | DMF | Probe (VCX 500) | 500 W, 20 kHz | 35% | 70 | – | – | 979 | [101] | |
CPO-27(Co) | Cobalt nitrate hexahydrate | 2,5-dihydroxyterephthalic acid | Water | DMF | Probe (VCX 500) | 500 W, 20 kHz | 35% | 70 | – | – | 1083 | [101] | |
CPO-27(Ni) | Nickel nitrate hexahydrate | 2,5-dihydroxyterephthalic acid | Water | DMF | Probe (VCX 500) | 500 W, 20 kHz | 35% | 70 | – | – | 1113 | [101] |
*1,4- bis(4-pyridyl)-2,3-diaza-1,3-butadiene.