Table 7.

Summary of MOF with electrochemical synthesis.

a. Anodic deposition
MOF	Metal source	Ligand	Solvent	Electolyte	Voltage (V)	Current (mA)	Time (min)	Temperature (℃)	Productivity (g h−1)	Surface area (m2 g−1)	Ref
HKUST-1	Cu plate (5 mm)	Trimesic acid	MeOH	–	19–12	1.3 A	150	–	–	1820	[102]
HKUST-1	Cu plate	Trimesic acid	EtOH/Water	MTBS*	2–30	50	–	40	0.215	1404	[107]
ZIF-8	Zinc plate	2-methylimidazole	DMF	MTBS	–	50	–	25	0.25	1656	[107]
MIL-100(Al)	Aluminium plate	Trimesic acid	EtOH/Water	–	–	–	–	60	–	969	[107]
MIL-53(Al)	Aluminium plate	Terephthalic acid	Water/DMF	KCl	–	10–100	–	90	0.775	910	[107]
NH2-MIL-53(Al)	Aluminium plate	2-Aminoterephthalic acid	Water/DMF	KCl	–	10–100	–	20–90	–	875	[107]
Zn3(BTC)2	Zinc plate	Trimesic acid	Water	NH4F	2	–	40 s	65	–	–	[108]
ZIF-4	Zinc foil	Imidazole	DMF/Water	MTBAMS**	2.5	–	15–60	85	–	75	[109]
ZIF-7	Zinc foil	Benzimidazole	DMF	MTBAMS	2.5	–	120	55	–	358	[109]
ZIF-8	Zinc foil	2-methylimidazole	Water	MTBAMS	2.5	–	60	55	–	1730	[109]
ZIF-14	Zinc foil	2-ethylimidazole	DMF/Water	MTBAMS	2.5	–	60	85	–	598	[109]
ZIF-67	Cobalt foil	2-methylimidazole	DMF/Water	MTBAMS	2.5	–	60–300	55–100	–	1521	[109]
*methyltributylammonium methyl sulfate, **methyltributylammonium methyl sulphate

b. Cathodic deposition
MOF	Metal source	Ligand	Solvent	Electolyte	Substrate	Ref
MOF-5	Zinc nitrate hexahydrate	Terephthalic acid	DMF	(NBu4)PF4	FTO	[106]
MOF-5	Zinc nitrate hydrate	Terephthalic acid	DMF/water	TBAPF6	FTO	[110]
MOF-5	Zinc Chloride	Terephthalic acid	DMF/water	TBAPF6	FTO	[110]
MOF-5	Zinc nitrate hexahydrate	Terephthalic acid	DMF	TBAPF6	FTO	[111]
IRMOF-3	Zinc nitrate hydrate	2-Aminoterephthalic acid	DMF/water	TBAPF6	FTO	[111]