Table 8.
Summary of MOF synthesized by Ball-mill (mechanochemical synthesis).
| MOF | Metal source | Ligand | M:L ratio | Reactor size (mL) | Solvent | Ion | By-product | Time | Temperature (℃) | Rotational speed | Yield (g) | Yield (%) | Surface area (m2 g−1) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Cu(INA)2 | Copper acetate monohydrate | Isonicotinic acid(INA) | 1:2 | 20 | – | – | Water, Acetic acid | 10 min | – | 25 Hz | – | – | – | [117] |
| MOF-5 | Zinc acetate dihydrate | Terephthalic acid | 3:1 | 80 | – | – | – | 60 min | – | 1100 rpm | – | – | 3465.9 | [49] |
| HKUST-1 | Copper acetate monohydrate | Trimesic acid | 3:2 | 10 | EtOH | – | Water, Acetic acid | 25 min | – | 25/40 Hz | – | – | 1713 | [112] |
| MOF-14 | Copper acetate monohydrate | H3BTB | 3:2 | 10 | EtOH | – | Water, Acetic acid | 25 min | – | 25/40 Hz | – | – | 628 | [112] |
| Ni-MOF | Nickel(II) acetate tetrahydrate | Trimesic acid | 3:2 | 80 | Water | – | – | 1–180 min | – | 10–50 Hz | – | 79.76 | 10.08 | [118] |
| UiO-66 | Zirconium(IV) propoxide/Methacrylic acid | Terephthalic acid | 1:6 | 10 | MeOH | – | – | 75 min | – | 30 Hz | 2.85 | – | 1020 | [119] |
| NH2-UiO-66 | Zirconium(IV) propoxide/Methacrylic acid | 2-aminoterephthalic acid | 1:6 | 10 | MeOH | – | – | 42 min | – | 30 Hz | 1.34 | – | 945 | [119] |
| Zn2(ta)2(dabco) | Zinc oxide | Terephthalic acid (ta) Triethylenediamine (dabco) |
1:1:0.5 | – | DMF | NaNO3 | – | 60 min | 20–25 | 30 Hz | – | – | – | [113] |