Table 9.
Summary of MOF synthesized by column reactor, counter current mixing reactor, and continuous stirred tank reactor.
| Reactor type | MOF | Time | Pressure | Reactor size | Temperature (℃) | Solvent | STY (kg m−3 day−1) | Productivity (g h−1) | Yield (%) | Surface area (m2 g−1) | Ref |
|---|---|---|---|---|---|---|---|---|---|---|---|
| Column Reactor | HKUST-1 | 5 min (reaction) | – | 1.59 mm ID, 30 cm | 60 (60–160) | EtOH/Water | – | 2 | 97 | 1673 | [121] |
| Column Reactor | MIL-53(Al) | 5–6 min(reaction) | 230 bar | 0.370 in ID, 20.3 mL | 250 (200–300) | Water | 1,300 | – | 86 | 1010 | [122] |
| Column Reactor | HKUST-1 | – | 75 bar | 0.370 in ID, 20.3 mL | 300 (200–300) | EtOH | 730 | – | 63 | 1554 | [122] |
| Counter current mixing reactor | HKUST-1 | – | 250 bar | – | 300 (100–400) | DMF/EtOH/Water | – | 132 | – | 1950 | [123] |
| Counter current mixing reactor | CPO-27 | – | – | – | 200 | DMF/Water | – | – | – | 1030 | [123] |
| Counter current mixing reactor | ZIF-8 | 1 min (reaction) | 240 bar | 55 mL | 100 | Water | 3,875 | 810 | – | 1800 | [124] |
| Continuous stirred tank reactor | MOF-5 | 4 h (residence) | atmospheric pressure | Conical flask | 100 (reflux) | DMF/DEF | 984 | 4 | – | 2302 | [126] |