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. 2020 Sep 18;426:213544. doi: 10.1016/j.ccr.2020.213544

Table 10.

Summary of MOF synthesized by tubular flow reactor.

Energy source MOF Residence time (min) Tube material Tube size Temperature (℃) Solvent STY (kg m−3 day−1) Productivity (g h−1) Yield (%) Surface area (m2 g−1) Ref
Heat HKUST-1 (macroscale) 1.2 PFA 1.0 mm ID/20 mL 140 EtOH 4,533 61.2 100 1805 [127]
Heat HKUST-1 (mesoscale) 10 PFA 1.0 mm ID/20 mL 80 EtOH 592 1.48 74 1852 [127]
Heat UiO66 (mesoscale) 10 PFA 1.0 mm ID/20 mL 130 DMF 672 1.68 67 1186 [127]
Heat NOTT-400 (mesoscale) 115 PFA 1.0 mm ID/30 mL 85 DMF/THF/water 741 2.78 61 1078 [127]
Heat Al-Fum 1 Stainless-steel 1.0 mm ID/10 mL 65 water 81,120 1070 [128]
Heat Al-Fum 1.2 Stainless-steel 6.0 mm ID/107 mL 65 water 73,009 1015 [128]
Heat Al-Fum 0.9 Stainless-steel 4.5 mm ID/374 mL 65 water 75,247 1082 [128]
Heat Al-Fum 1 Stainless-steel 10.9 mm ID/1394mL 65 water 97,159 5,600 1054 [128]
Heat UiO-66 0.44 0.8 mm ID 120 DMF 1206 [130]
Heat ZIF-8 15 s PFA 1.6 mm/3mL RT MeOH/NH3 210,000 15,360 54 1770 [131]
Heat Ce-BDC 30 s Stainless-steel 0.5 mm ID/1m 250 DMF [132]
Microwave UiO-66 7 (mw: 73 min) PTFE 4.35 mm ID/53 mL 200 W,3bar DMF 7,204 14.4 94 1052 [129]
Microwave MIL-53(Al) 4 (mw: 34 min) PTFE 4.35 mm ID/53 mL 200 W, 6 bar DMF 3,618 7.1 65 1376 [129]
Microwave HKUST-1 1 (mw: 17 min) PTFE 4.35 mm ID/29.6 mL 360 W,6bar DMF 64,800 79.4 96 1550 [129]