Table 12.
Summary of binder selection for shaping processes.
|
a. Polymer binder | ||||||
|---|---|---|---|---|---|---|
| Binder | MOF | Ratio of MOF/Binder | S. A. Before | S. A. After | Process time | Ref |
| Polyvinyl group | MIL-125-NH2 | 97% | 1259 | 930 | – | [154] |
| Polyvinyl alcohol (PVA) | UiO-66 | 22 vol% | 710 | 359 | 30 min | [155] |
| Polysiloxane | UiO-66 | 72.5 vol% | 710 | 418 | 30 min | [155] |
| Polyvinyl Butyral (PVB) | SIFSIX-3-Ni | – | 360 | 297 | – | [156] |
| Polyvinyl Butyral (PVB) | SIFSIX-2-Cu-i | – | 808 | 685 | – | [156] |
| Polyvinyl Butyral (PVB) | GeFSIX-2-Cu-i | – | 755 | 659 | – | [156] |
| Polyvinyl Butyral (PVB) | TIFSIX-2-Cu-i | – | 740 | 719 | – | [156] |
| Polyvinyl Butyral (PVB) | Mg-MOF-74 | – | 915 | – | – | [156] |
| Polyvinyl Butyral (PVB) | HKUST-1 | – | – | – | – | [156] |
| Polyvinylchloride (PVC) | ZIF-8 | 7.5/15/30 wt% | – | – | – | [157] |
| Polyvinylformal (PVF) | ZIF-8 | 7.5/15/30 wt% | – | – | – | [157] |
| Polyetherimide (PEI) | ZIF-8 | 7.5/15/30 wt% | – | – | – | [157] |
| Polystyrene (PS) | ZIF-8 | 7.5/15/30 wt% | – | – | – | [157] |
| Cellulose-acetate (CA) | ZIF-8 | 7.5/15/30 wt% | – | – | – | [157] |
| Acrylonitrile butadiene styrene (ABS) | MOF-5 | 1% | – | – | – | [158] |
| Acrylonitrile butadiene styrene (ABS) | MOF-5 | 5% | – | – | – | [158] |
| Acrylonitrile butadiene styrene (ABS) | MOF-5 | 10% | – | – | – | [158] |
| Sucrose | UiO-66 | 90 wt% | 1367 | 674 | 1 d | [159] |
| TENAX | (CO)MOF-74 | 14 wt% | 86 | 55 | 1 d | [160] |
| TENAX | (Zn)ZIF-8 | 8.4 wt% | – | – | 1 d | [160] |
| TENAX | (CO)ZIF-67 | 9.6 wt% | – | – | 1 d | [160] |
| TENAX | (Zr)UiO-66 | 8.4 wt% | – | – | 1 d | [160] |
| b. Inorganic binder | ||||||
| Binder | MOF | Ratio of MOF/Binder | S. A. Before | S. A. After | Process time | Ref |
| Mesoporous Rho Alumina (MRA) | MiL-100(Fe) | 95 wt% | 2088 | 1831 | 12 h | [161] |
| Mesoporous Rho Alumina (MRA) | MiL-101(Cr) | 95 wt% | 4066 | 3685 | 12 h | [161] |
| Mesoporous Rho Alumina (MRA) | UiO-66 | 95 wt% | 1050 | 911 | 12 h | [161] |
| Mesoporous Rho Alumina (MRA) | UiO-66-NH2 | 95 wt% | 875 | 823 | 12 h | [161] |
| Bentonite clay | MIL-101(Cr) | 60% | 202.22 | 182.84 | several days | [162] |
| Bentonite clay | MIL-101(Cr) | 75% | 202.22 | 182.84 | several days | [162] |
| Graphite | UiO-66 | 99% | 1140 | 885 | – | [163] |
| silica sol | MiL-100(Fe) | 90% | 1772 | 1619 | 12 h | [164] |
| Silres MSE 100 (CH3Si(O)1.1(OCH3)0.8) | HKUST-1 | 88% | – | – | 20 min | [165] |
| c. Binderless (Binder-free) | ||||||
| Binder | MOF | Ratio of MOF/Binder | S. A. Before | S. A. After | Process time | Ref |
| Binder-free | MOF-5 | – | 2750 | 2600 ~ 1200 | – | [166] |
| CPO-27-Ni | – | 1060 | 1050 | 30 min | [167] | |
| CuBTC (Basolite™ C300) | – | – | – | – | [168] | |
| MIL-53(Al) | – | – | – | – | [168] | |
| HKUST-1 | – | – | – | 3 h | [169] | |
| UiO-66 | – | 1175 | 511/417 | 6–18 h | [155] | |
| HKUST-1 | – | – | – | 11 h | [170] | |
| ZIF-8HT | – | – | 1387 | 1 d | [170] | |
| ZIF-8LT | – | – | 1359 | 1 d | [171] | |
| ZIF-8LT-HT | – | – | 1423 | 1 d | [171] | |
| ZIF-8ER | – | – | 1395 | 1 d | [171] | |