Table 14.
Summary of shaping process; Non-pressurized processes with binders.
| d. Non pressurized processes with binders | |||||
|---|---|---|---|---|---|
| Process type | MOF | Binder | Ratio of MOF/Binder | Shape | Ref |
| homemade fan-type granulator | MiL-125-NH2 | 3 wt% polyvinyl group | 97 wt% | Granules | [154] |
| granulation | UiO-66 | Poly(vinyl alcohol) 4 vol% | 22 vol% | Granules | [155] |
| Extrusion | UiO-66 | Poly(vinyl alcohol) 4 vol% | 22 vol% | Cylindrical garanules | [155] |
| Freeze granulation | UiO-66-COOH | Polyvinyl alcohole | 22 vol% | Bead | [155] |
| Extrudate | UiO-66-COOH | polysiloxane (silicon resin)-based binder | 72.5 vol% | Cylinder | [155] |
| Extrusion molding | SIFSIX-3-Ni | 8 wt% polyvinyl butyral (PVB) | 90 wt% | Pellet | [156] |
| Extrusion molding | SIFSIX-2-Cu-i | 8 wt% polyvinyl butyral (PVB) | 90.8 wt% | Pellet | [156] |
| Extrusion molding | GeFSIX-2-Cu-i | 8 wt% polyvinyl butyral (PVB) | 89.6 wt% | Pellet | [156] |
| Extrusion molding | TIFSIX-2-Cu-i | 8 wt% polyvinyl butyral (PVB) | 89.4 wt% | Pellet | [156] |
| Extrusion molding | HKUST-1 | 8 wt% polyvinyl butyral (PVB) | 90 wt% | Pellet | [156] |
| Extrusion molding | Mg-MOF-74 | 8 wt% polyvinyl butyral (PVB) | 90 wt% | Pellet | [156] |
| Extrusion-crushing-sieving(ECS) | ZIF-8 | CA (cellulose-acetate) | 7.5/15/30 wt% | Pellet | [157] |
| Extrusion-crushing-sieving(ECS) | ZIF-8 | PVC (polyvinylchloride) | 7.5/15/30 wt% | Pellet | [157] |
| Extrusion-crushing-sieving(ECS) | ZIF-8 | PVF (polyvinylformal) | 7.5/15/30 wt% | Pellet | [157] |
| Extrusion-crushing-sieving(ECS) | ZIF-8 | PEI (polyetherimide) | 7.5/15/30 wt% | Pellet | [157] |
| Extrusion-crushing-sieving(ECS) | ZIF-8 | PS (polystyrene) | 7.5/15/30 wt% | Pellet | [157] |
| Extrusion | MOF-5 | 99% ABS (acrylonitrile butadiene styrene) | 1% | Filament | [158] |
| Extrusion | MOF-5 | 95% ABS | 5% | Filament | [158] |
| Extrusion | MOF-5 | 90% ABS | 10% | Filament | [158] |
| Granulation | UiO66 | 10 wt% sucrose | 90 wt% | Pellet | [159] |
| Casting on pellet | (CO)MOF-74 | TENAX (80–100 mesh pellet) | 14 wt% | Pellet | [160] |
| Casting on pellet | (Zn)ZIF-8 | TENAX (80–100 mesh pellet) | 8.4 wt% | Pellet | [160] |
| Casting on pellet | (CO)ZIF-67 | TENAX (80–100 mesh pellet) | 9.6 wt% | Pellet | [160] |
| Casting on pellet | (Zr)UiO-66 | TENAX (80–100 mesh pellet) | 8.4 wt% | Pellet | [160] |
| Hand-made pan-type granulator | MiL-100(Fe) | 5 wt% MRA (Mesoporous ρ Alumina) | 95 wt% | Sphere | [161] |
| Hand-made pan-type granulator | MiL-101(Cr) | 5 wt% MRA (Mesoporous ρ Alumina) | 95 wt% | Sphere | [161] |
| Hand-made pan-type granulator | UiO-66 | 5 wt% MRA (Mesoporous ρ Alumina) | 95 wt% | Sphere | [161] |
| Hand-made pan-type granulator | UiO66-NH2 | 5 wt% MRA (Mesoporous ρ Alumina) | 95 wt% | Sphere | [161] |
| Extrusion | MIL-101(Cr) | 40 wt% bentonite clay | 60 wt% | Monolith | [162] |
| Extrusion | MIL-101(Cr) | 25 wt% bentonite clay | 75 wt% | Monolith | [162] |
| Rotary press tabletilizer | UiO66 | 1 wt% graphite | 99% | Tablet | [163] |
| Wet granulation | MiL-125(Fe) | 10% silica sol | 90 wt% | Granules | [164] |
| Extrusion | HKUST-1 | Silres MSE 100 (CH3Si(O)1.1 (OCH3)0.8 | 88% | Monolith | [165] |
| Xero gel | MIL-100(Fe) | resorcinol formaldehyde based Xerogel | 57% | Cylindrical monolith | [176] |
| Xero gel | MIL-100(Fe) | resorcinol formaldehyde based Xerogel | 50% | Cylindrical monolith | [176] |
| Xero gel | MIL-100(Fe) | resorcinol formaldehyde based Xerogel | 42% | Cylindrical monolith | [176] |
| Xero gel | MIL-100(Cr) | resorcinol formaldehyde based Xerogel | 57% | Cylindrical monolith | [176] |
| Xero gel | MIL-100(Cr) | resorcinol formaldehyde based Xerogel | 49% | Cylindrical monolith | [176] |
| Xero gel | MIL-100(Cr) | resorcinol formaldehyde based Xerogel | 44% | Cylindrical monolith | [176] |
| Xero gel | MIL-101(Cr) | resorcinol formaldehyde based Xerogel | 65% | Cylindrical monolith | [176] |
| Xero gel | MIL-101(Cr) | resorcinol formaldehyde based Xerogel | 54% | Cylindrical monolith | [176] |
| Xero gel | MIL-101(Cr) | resorcinol formaldehyde based Xerogel | 50% | Cylindrical monolith | [176] |
| Xero gel | MIL-101(Cr) | resorcinol formaldehyde based Xerogel | 33% | Cylindrical monolith | [176] |