Table 19.

Type of VOC and its adsorption capacity on MOFs.

MOF adsorbents	Adsorbate	Temperature (K)	Capacity (mmol g−1)	Ref
MIL (Cr)-Z1	Benzene	293	~7.0	[267]
UiO-66	Toluene	298	1.8	[268]
UiO-66(NH2)	Toluene	298	2.7	[268]
MOF-199	Toluene	298	1.7	[268]
ZIF-67	Toluene	298	2.4	[268]
MIL-101(Fe)	Toluene	298	1.1	[268]
MOF-5	Toluene	298	0.3	[268]
MIL-101	Benzene	298	16.3	[269]
MIL-101	Boluene	298	13.6	[269]
MIL-101	Ethyl benzene	298	12	[269]
MIL-101@GO	Benzene	298	20	[269]
MIL-101@GO	Toluene	298	16.6	[269]
MIL-101@GO	Ethyl benzene	298	13.6	[269]
BUT-66	Benzene	298	3.9	[270]
BUT-66	Benzene	298	2.5a	[270]
BUT-67	Benzene	298	6.1	[270]
MIL-100(Fe)_A2	Toluene	298	5.6	[271]
MIL-125 NH2	Benzene	298	4	[272]
MIL-125 NH2	Toluene	298	3.1	[272]
MIL-125 NH2	p-Xylene	298	2.8	[272]
MIL-125 NH2	Acetone	298	6.1	[272]
MIL-125 NH2	2-Propanol	298	5.3	[272]
MIL-125 NH2	Formaldehyde	298	1.3	[272]
CAU-1	Toluene	298	0.07b	[273]
HKUST-1**	Toluene	298	1.6	[274]
Foam HK@CMC**	Toluene	298	3.1	[274]
Foam HK@CMC-SA**	Toluene	298	2.1	[274]
Foam HK@CMC-CS**	Toluene	298	2.79	[274]
MIL-101	Acetone c	288	16.3	[275]
MIL-101/TC-30	Acetone c	288	19.3	[275]
MIL-101/TC-40	Acetone c	288	19.5	[275]
MIL-101/TC-50	Acetone c	288	13.2	[275]
M-UiO-66(Zr-N3.0)	Acetaldehyde	298	9.4	[276]
M-UiO-66(Zr-N3.0)	Chlorobenzene	298	4.9	[276]
UiO-66-NH2	Formaldehyde	298	2.3	[277]
γ-CD-MOF-K	Formaldehyde	293	1.2	[278]
Al-fumarate MOF	Dichloromethane	298	3.4	[279]
MIL-101	Carbon tetrachloride	303	13.3	[280]
MIL-101/GrO-0.25	Carbon tetrachloride	303	15.4	[280]

^a(0.012 kPa, 25C), ^b50% RH, toluene (1 ppm), ^c18.1 kPa, **HKUST-1 was synthesized by using Cu(OAc)₂.