Table 22.
a. Proton conducting MOFs | ||||
---|---|---|---|---|
MOF compound | Pore guest | Proton conductivity | Conditions [Temperature/humidity] | Ref |
Mg(HCO2)2 | H2O | 1.0 × 10−3 | 25 °C, 90% RH | [335] |
Co(HCO2)2 | H2O | 1.0 × 10−6 | 25 °C, 90% RH | [335] |
Cr/sBDC-Gel-0.4 M | H3O+ | 7.84 × 10−3 | 80 °C, 100% RH | [336] |
α-PCMOF-21-Br | H2O | 1.69 × 10−3 | 85 °C, 95% RH | [337] |
α-PCMOF-21-Cl | H2O | 0.95 × 10−3 | 85 °C, 95% RH | [337] |
UiO-66-NH2@NFs/Nafion | H3O+ | 0.27 | 80 °C, 100% RH | [340] |
PSM 1 | H2O | 1.64 × 10−1 | 80 °C, 95% RH | [341] |
IM-UiO-66-AS | H2O | 1.54 × 10−1 | 80 °C, 98% RH | [342] |
(EMI)[N(CN)2]@PCN-777 (f = 62.5%) | EMI-N(CN)2 | 1.1 × 10−2 | 70 °C | [343] |
(NH4)3[Zr(H2/3PO4)3] | NH4+ | 1.45 × 10−3 | 180 °C | [344] |
DNA@ZIF-8–3/25 | DNA, H2O | 1.7 × 10−1 | 75 °C, 97% RH | [345] |
MOF-801@PP-60 | H2O | 1.84 × 10−3 | 325 K, 98% RH | [346] |
SA-EIMS@MIL-101 | R-SO3− | 1.89 × 10−3 | 150 °C | [347] |
MSA-EIMS@MIL-101 | R-SO3− | 1.02 × 10−4 | 150 °C | [347] |
PTSA-EIMS@MIL-101 | R-SO3− | 2.78 × 10−4 | 150 °C | [347] |
b. MOF based SSEs | ||||
MOF compound | Pore guest | Ionic conductivity | Transference number | Ref |
LCMOF-1 (–COOH) | Li+ | 1.06 × 10−3, 25 °C | 0.58 | [348] |
UiO-66-LiSS | Li+ | 6.0 × 10−5, 25 °C | 0.9 | [349] |
UiO-66-LiSS-EC/PC | Li+ | 7.8 × 10−4, 25 °C | 0.88 | [349] |
NMS/PEO/LiTFSI | Li+ | 1.66 × 10−5, 25 °C | 0.378 | [350] |
MOF-688 | Li+ | 4.6 × 10−4, 30 °C | 0.87 | [338] |
PL/UiOLiTFS | Li+ | 2.07 × 10−4, 25 °C | 0.84 | [333] |
WZM SSE | Zn2+ | 2.1 × 10−4, 35 °C | 0.93 | [339] |
UIO/IEs | Li+ | 1.47 × 10−4, 30 °C | 0.47 | [351] |
ZIF-8 QSSE | Li+ | 1.05 × 10−4, 25 °C | 0.52 | [352] |
Al-Td-MOF-1 | Li+ | 5.7 × 10−5, 25 °C | – | [353] |
MIT-20LiBr | Li+ | 4.4 × 10−5, 25 °C | 0.66 | [354] |
MIT-20-Na | Na+ | 1.8 × 10−5, 25 °C | – | [354] |
MIT-20-Mg | Mg2+ | 8.8 × 10−7, 25 °C | – | [354] |