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. 2020 Sep 18;426:213544. doi: 10.1016/j.ccr.2020.213544

Table 22.

Conductivity and conduction medium of ion conducting MOFs.

a. Proton conducting MOFs
MOF compound Pore guest Proton conductivity Conditions [Temperature/humidity] Ref
Mg(HCO2)2 H2O 1.0 × 10−3 25 °C, 90% RH [335]
Co(HCO2)2 H2O 1.0 × 10−6 25 °C, 90% RH [335]
Cr/sBDC-Gel-0.4 M H3O+ 7.84 × 10−3 80 °C, 100% RH [336]
α-PCMOF-21-Br H2O 1.69 × 10−3 85 °C, 95% RH [337]
α-PCMOF-21-Cl H2O 0.95 × 10−3 85 °C, 95% RH [337]
UiO-66-NH2@NFs/Nafion H3O+ 0.27 80 °C, 100% RH [340]
PSM 1 H2O 1.64 × 10−1 80 °C, 95% RH [341]
IM-UiO-66-AS H2O 1.54 × 10−1 80 °C, 98% RH [342]
(EMI)[N(CN)2]@PCN-777 (f = 62.5%) EMI-N(CN)2 1.1 × 10−2 70 °C [343]
(NH4)3[Zr(H2/3PO4)3] NH4+ 1.45 × 10−3 180 °C [344]
DNA@ZIF-8–3/25 DNA, H2O 1.7 × 10−1 75 °C, 97% RH [345]
MOF-801@PP-60 H2O 1.84 × 10−3 325 K, 98% RH [346]
SA-EIMS@MIL-101 R-SO3 1.89 × 10−3 150 °C [347]
MSA-EIMS@MIL-101 R-SO3 1.02 × 10−4 150 °C [347]
PTSA-EIMS@MIL-101 R-SO3 2.78 × 10−4 150 °C [347]



b. MOF based SSEs

MOF compound Pore guest Ionic conductivity Transference number Ref

LCMOF-1 (–COOH) Li+ 1.06 × 10−3, 25 °C 0.58 [348]
UiO-66-LiSS Li+ 6.0 × 10−5, 25 °C 0.9 [349]
UiO-66-LiSS-EC/PC Li+ 7.8 × 10−4, 25 °C 0.88 [349]
NMS/PEO/LiTFSI Li+ 1.66 × 10−5, 25 °C 0.378 [350]
MOF-688 Li+ 4.6 × 10−4, 30 °C 0.87 [338]
PL/UiOLiTFS Li+ 2.07 × 10−4, 25 °C 0.84 [333]
WZM SSE Zn2+ 2.1 × 10−4, 35 °C 0.93 [339]
UIO/IEs Li+ 1.47 × 10−4, 30 °C 0.47 [351]
ZIF-8 QSSE Li+ 1.05 × 10−4, 25 °C 0.52 [352]
Al-Td-MOF-1 Li+ 5.7 × 10−5, 25 °C [353]
MIT-20LiBr Li+ 4.4 × 10−5, 25 °C 0.66 [354]
MIT-20-Na Na+ 1.8 × 10−5, 25 °C [354]
MIT-20-Mg Mg2+ 8.8 × 10−7, 25 °C [354]