Table A1.
Membrane (Reference) |
Type | Electrolyte | Seebeck Coefficient () |
Electrodes | |
---|---|---|---|---|---|
Collodion Ikeda [24] |
KCl | M | 0.052 | Ag|AgCl | |
Oxidized collodium Ikeda [61] |
Apparent transport number 0.9 | KCl | M | 0.03 | Calomel |
PMA Laksminarayanaiah [26] |
Crosslinked polymetrarylic acid | LiCl | M | 1.00 | Ag|AgCl |
NaCl | 0.97 | ||||
KCl | 0.95 | ||||
RbCl | 0.77 | ||||
CsCl | 0.82 | ||||
Amberlite XE-69-polyvinyl chloride 40% Tasaka et al. [30,31] |
Heterogeneous polystyrenesulfonate | LiCl | M | 0.70 | Calomel |
M | 0.60 | ||||
M | 0.52 | ||||
M | 0.42 | ||||
NaCl | M | 0.81 | |||
M | 0.70 | ||||
M | 0.60 | ||||
M | 0.50 | ||||
KCl | M | 0.85 | |||
M | 0.72 | ||||
M | 0.66 | ||||
M | 0.54 | ||||
KBr | M | 0.83 | |||
M | 0.75 | ||||
M | 0.65 | ||||
M | 0.50 | ||||
KI | M | 0.83 | |||
M | 0.75 | ||||
M | 0.65 | ||||
M | 0.55 | ||||
o-m-1 Tasaka et al. [30,33] |
Oxidized Collodion | KCl | M | 0.27 | Calomel |
M | 0.17 | ||||
M | 0.13 | ||||
M | 0.07 | ||||
i-m-1 Tasaka et al. [33] |
Collodion-sulfonated Polystyrene interpolymer | KCl | M | 0.15 | Calomel |
M | 0.11 | ||||
M | 0.05 | ||||
M-10/0 Tasaka [34,37] |
Heterogeneous Sulfonate polystyrene+ PVC (40%) | LiCl | M | 0.70 | Calomel |
NaCl | 0.80 | ||||
KCl | 0.84 | ||||
RbCl | 0.89 | ||||
CsCl | 0.95 | ||||
NHCl | 0.93 | ||||
Nepton CR-61 Tasaka [37] |
Homogeneous Sulfonate polystyrene | KCl | M | 0.66 | Calomel |
Nepton CR-51 Tasaka [37] |
Homogeneous Sulfonated phenol resin | KCl | M | 0.63 | Calomel |
Interpolymer Tasaka [37] |
Sulfonated polystyrene + dried collodion (95%) | KCl | M | 0.49 | Calomel |
Flemion S Hanaoka et al. [46] |
Porous perfluorosulfonic acid-type | HCl | M | 0.053 | Calomel |
LiCl | 0.48 | ||||
NaCl | 0.46 | ||||
KCl | 0.59 | ||||
NHCl | 0.62 | ||||
Nafion 117 Kjelstrup et al. [47] |
Homogeneous Sulfonated | HCl | M | 0.66 | Ag|AgCl |
Ionics 61 CZL 386 Barragán et al. [48] |
Heterogeneous sulfonated | KCl | M | 0.53 | Calomel |
M | 0.51 | ||||
M | 0.45 | ||||
M | 0.42 | ||||
M | 0.39 | ||||
LiCl | M | 0.75 | |||
NaCl | 0.66 | ||||
KCl | 0.51 | ||||
CsCl | 0.44 | ||||
Nafion 1110 Kjelstrup et al. [14] |
Homogeneous Sulfonated | HCl | 0.67 | Hydrogen |