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. 2018 Nov 26;20(12):905. doi: 10.3390/e20120905

Table A1.

Seebeck coefficient, (Δϕ/ΔT), for cation-exchange membranes.

Membrane
(Reference)
Type Electrolyte Seebeck Coefficient
(103VK1)
Electrodes
Collodion
Ikeda [24]
KCl 1.0×101 M 0.052 Ag|AgCl
Oxidized collodium
Ikeda [61]
Apparent transport number 0.9 KCl 1.0×101 M 0.03 Calomel
PMA
Laksminarayanaiah [26]
Crosslinked polymetrarylic acid LiCl 1.0×102 M 1.00 Ag|AgCl
NaCl 0.97
KCl 0.95
RbCl 0.77
CsCl 0.82
Amberlite XE-69-polyvinyl chloride 40%
Tasaka et al. [30,31]
Heterogeneous polystyrenesulfonate LiCl 1.0×103 M 0.70 Calomel
5.0×103 M 0.60
1.0×102 M 0.52
5.0×102 M 0.42
NaCl 1.0×103 M 0.81
5.0×103 M 0.70
1.0×102 M 0.60
5.0×102 M 0.50
KCl 1.0×103 M 0.85
5.0×103 M 0.72
1.0×102 M 0.66
5.0×102 M 0.54
KBr 1.0×103 M 0.83
5.0×103 M 0.75
1.0×102 M 0.65
5.0×102 M 0.50
KI 1.0×103 M 0.83
5.0×103 M 0.75
1.0×102 M 0.65
5.0×102 M 0.55
o-m-1
Tasaka et al. [30,33]
Oxidized Collodion KCl 1.0×103 M 0.27 Calomel
5.0×103 M 0.17
1.0×102 M 0.13
5.0×102 M 0.07
i-m-1
Tasaka et al. [33]
Collodion-sulfonated Polystyrene interpolymer KCl 5.0×103 M 0.15 Calomel
1.0×102 M 0.11
5.0×102 M 0.05
M-10/0
Tasaka [34,37]
Heterogeneous Sulfonate polystyrene+ PVC (40%) LiCl 1.0×103 M 0.70 Calomel
NaCl 0.80
KCl 0.84
RbCl 0.89
CsCl 0.95
NH4Cl 0.93
Nepton CR-61
Tasaka [37]
Homogeneous Sulfonate polystyrene KCl 1.0×103 M 0.66 Calomel
Nepton CR-51
Tasaka [37]
Homogeneous Sulfonated phenol resin KCl 1.0×103 M 0.63 Calomel
Interpolymer
Tasaka [37]
Sulfonated polystyrene + dried collodion (95%) KCl 1.0×103 M 0.49 Calomel
Flemion S
Hanaoka et al. [46]
Porous perfluorosulfonic acid-type HCl 1.0×102 M 0.053 Calomel
LiCl 0.48
NaCl 0.46
KCl 0.59
NH4Cl 0.62
Nafion 117
Kjelstrup et al. [47]
Homogeneous Sulfonated HCl 1.0×102 M 0.66 Ag|AgCl
Ionics 61 CZL 386
Barragán et al. [48]
Heterogeneous sulfonated KCl 7.5×104 M 0.53 Calomel
1.0×103 M 0.51
2.5×103 M 0.45
5.0×103 M 0.42
7.5×101 M 0.39
LiCl 1.0×103 M 0.75
NaCl 0.66
KCl 0.51
CsCl 0.44
Nafion 1110
Kjelstrup et al. [14]
Homogeneous Sulfonated HCl 0.67 Hydrogen