Table 1. 1H, 13C (italic) and 31P (bold) Chemical Shift Values of the Saccharide Region of the LPSBv.
chemical shifts (δ) |
||||||||
---|---|---|---|---|---|---|---|---|
unit | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 |
A, 6-α-GlcpN | 5.5 | 3.22 | 3.81 | 3.27 | 4.07 | 4.12/3.80 | ||
90.4 | 54.3 | 69.9 | 70.1 | 73 | 68 | |||
2.99 | ||||||||
B, 6-β-GlcpN | 4.9 | 2.86 | 3.52 | 3.43 | 3.55 | 3.69/3.47 | ||
99.6 | 55.6 | 72.3 | 69.8 | 74.5 | 61.3 | |||
C, 3,4-α-Rhap (α-RhaI) | 5.11 | 4.16 | 3.96 | 3.85 | 3.85 | 1.23 | ||
101 | 70.2 | 78.9 | 73.6 | 68.6 | 16.9 | |||
D, t-β-Galf | 5.07 | 4.06 | 3.96 | 3.92 | 3.72 | 3.56 | ||
108.6 | 81.8 | 77 | 82.8 | 70.3 | 62.7 | |||
E, t-α-Fucp | 5.09 | 3.67 | 3.76 | 3.71 | 4.27 | 1.14 | ||
99.4 | 68.3 | 71.4 | 73.2 | 66.9 | 16.2 | |||
F, 3-β-Glcp | 4.47 | 3.29 | 3.48 | 3.36 | 3.36 | 3.82/3.62 | ||
102.5 | 73.5 | 82.4 | 69.9 | 75.6 | 60.8 | |||
G, t-α-Rhap (α-RhaII) | 5.01 | 3.93 | 3.81 | 3.34 | 3.96 | 1.22 | ||
100.8 | 70.4 | 69.7 | 71.9 | 67.4 | 17 | |||
G′, 4-α-Rhap (α-Rha′II) | 5 | 3.93 | ND | 3.58 | 3.88 | 1.22 | ||
100.8 | 70.4 | ND | 79.4 | 67.5 | 17 | |||
H, 2,6-β-Galp | 4.72 | 3.45 | 3.75 | 3.8 | 3.71 | 3.93 | ||
100.2 | 76.8 | 71.4 | 69.7 | 70.6 | 69 | |||
I, 4-α-Rhap (α-RhaOC) | 4.86 | 3.9 | 3.94 | 3.58 | 3.89 | 1.22 | ||
99.7 | 70.3 | 70.3 | 79.4 | 67.5 | 17 | |||
L, 3-β-Manp | 4.78 | 4.17 | 3.58 | 3.54 | 3.29 | 3.82/3.64 | ||
100.3 | 66.6 | 76.6 | 65 | 76.1 | 60.8 | |||
K, 5-α-Kdop | 1.77/2.02 | 4.15 | 4.07 | 3.68 | 3.96 | 3.95/3.86 | ||
34.5 | 67.2 | 73.3 | 70.5 | 70.2 | 65.6 | |||
1.64 |