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. Author manuscript; available in PMC: 2020 Sep 28.
Published in final edited form as: Chem Biodivers. 2009 Apr;6(4):527–539. doi: 10.1002/cbdv.200800277

Scheme 2. The Cleavage Mechanism of the GS-SG Intermediate Involves Disulfide Bond Reduction and Cleavage of Glutamic Acid.

Scheme 2.

a) 37°, 100 mm sodium phosphate buffer with three different pH values (6.2, 6.8, and 7.4).