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. Author manuscript; available in PMC: 2020 Sep 28.
Published in final edited form as: Nat Rev Chem. 2019 May 7;3(6):347–360. doi: 10.1038/s41570-019-0099-x

Figure 5. Overview of Rh2(DOSP)4-catalyzed intermolecular C–H functionalization.

Figure 5.

a: Favored sites for C–H Functionalization. b: Predictive model for the relative and absolute configuration for Rh2(DOSP)4-catalyzed C–H functionalization. The large (L) group points away from the catalyst, the medium (M) group is on the side of the aryl group, which is in the same plane as the rhodium-carbene, and the small (S) group is on the side on the esters group which is orthogonal to the rhodium carbene-aryl plane and points towards the approaching substrate.