Table 6.
Before biosorption | After biosorption | Shift | References | ||
---|---|---|---|---|---|
Wave no. (cm−1) | Annotations | Wave no. (cm−1) | Annotations | ||
3917 3905 3890 3868 3854 3841 3806 |
O–H stretching |
3959 3909 3899 3873 3862 3754 |
O–H stretching |
+ 42 + 4 + 9 + 5 + 8 –87 |
Andrews and Hunt73 |
3391 | O–H hydroxyl group | 3441 | broad band of OH and NH | + 50 | Widjanarko et al.74, El-Sheekh et al.75 |
– | – | 2974 | C–H | – | Khan et al. (2008)76 |
– | – | 2928 | C–H | – | Ouhaddouch et al.77 |
2354 | C–H stretching from aromatic group | 2359 | N–H or C=O stretching vibrations | + 5 | Maaz78, Raman79 |
1853 | C–H stretching in trans HC=CH | – | – | Sun80 | |
1658 | C=O, C=N stretching, NH2 bending (amide I and II) | 1644 | C=O Carbonil | –14 | Filip and Hermann81, Byler and Susi82 |
– | – | 1550 | Carbonates groups | – | Wilsona et al.83 |
1443 | C–H group (alkyl) | 1451 | Pure modes of CH2 | + 8 | Prosanov and Matvienko86, Pawlukojć et al.87 |
1329 | N–H group | 1266 | O–H stretching, NH bending (amide III), C=O, carboxylic groups | –63 | Greenwood88, Kumari et al.89 |
1095 | C–O stretching |
1146 1101 |
C–O–C C–O ring |
+ 51 + 6 |
Shao and Wei90, Kačuráková et al.91 |
748 | C–H wagging vibration | 660 | Carboxylic group (COO–) stretching vibration | –88 | Da Róz et al.92, Ramaswamy et al.93 |
618 | C–C twisting (protein) (alkanes) | 615 | C–H group, S–O bends inorganic sulfates | –3 | Rehman et al.94, Smidt and Meissl95 |
422 | C=N or O–H stretching | 475 | S–S band | + 53 | Kong and Shaoning97, Carpenter et al.99 |