Table 5. Glucose Formation Rate Constants of Malto-Oligosaccharides and Starch over the AC-SO3H, Amberlyst 70 and 0.01 M H2SO4a.
| rate
constant k/L mol–1 h–1 |
||||||
|---|---|---|---|---|---|---|
| saccharides | DP | k1: AC-SO3H | k2 (k2′): Amberlyst 70 | k3: 0.01 M H2SO4 | k1/k3 | k2/k3 |
| maltose | 2 | 45 | 20 (42) | 41 | 1.1 | 0.50 |
| maltotriose | 3 | 66 | 12 (29) | 34 | 1.9 | 0.34 |
| maltotetraose | 4 | 1.1 × 102 | 10 (n.d.) | 31 | 3.4 | 0.30 |
| maltopentaose | 5 | 2.2 × 102 | 9.2 (29) | 33 | 6.7 | 0.28 |
| starch | 30 | 1.4 × 103 | 14 (74) | 1.2 × 102 | 12 | 0.11 |
Reaction conditions: 0.5–25 mg saccharides, 20 mg catalyst, 2 mL distilled water (or dilute acid) at 120 °C for 10 min–12 h.