Table 1. Distribution Ratios for Extraction of Zn(II) by 0.2 mol L–1 TOMAC in Toluene from 30.6 mmol L–1 ZnCl2 in HCl or a Different Monovalent Salt and the Salt Cation Standard State Gibbs Free Energy of Hydration (ΔGhyd,exp0)32.
cation | DZn(II) at 4 mol L–1 chloride | ΔGhyd,exp0 (kJ mol–1) |
---|---|---|
H+ | (3.6 ± 0.2) · 102 | –1050 |
Li+ | (1.9 ± 0.1) · 103 | –475 |
Na+ | (1.3 ± 0.1) · 103 | –365 |
K+ | (5.8 ± 0.3)· 102 | –295 |
NH4+ | (5.4 ± 0.3)· 102 | –285 |
Rb+ | (3.4 ± 0.2) · 102 | –275 |
Cs+ | (7.5 ± 0.4) · 101 | –250 |