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. 2020 Aug 28;59(18):13442–13452. doi: 10.1021/acs.inorgchem.0c01821

Table 1. Distribution Ratios for Extraction of Zn(II) by 0.2 mol L–1 TOMAC in Toluene from 30.6 mmol L–1 ZnCl2 in HCl or a Different Monovalent Salt and the Salt Cation Standard State Gibbs Free Energy of Hydration (ΔGhyd,exp0)32.

cation DZn(II) at 4 mol L–1 chloride ΔGhyd,exp0 (kJ mol–1)
H+ (3.6 ± 0.2) · 102 –1050
Li+ (1.9 ± 0.1) · 103 –475
Na+ (1.3 ± 0.1) · 103 –365
K+ (5.8 ± 0.3)· 102 –295
NH4+ (5.4 ± 0.3)· 102 –285
Rb+ (3.4 ± 0.2) · 102 –275
Cs+ (7.5 ± 0.4) · 101 –250